Technical options of carbon and nitrogen removal in wastewater treatment

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1 Technical options of carbon and nitrogen removal in wastewater treatment PRESTO Training workshop Minsk/ Belarus, Dr.-Ing. Peter Hartwig

2 Independent Consulting and Planning Engineers for Water, Wastewater, Solid Waste and Environmental Protection Technology Worldwide Experience from the planning and realization of more than 1,000 projects in the field of environmental protection in the last 30 years

3 Fields of specialization Consulting for Environmental Protection Industrial wastewater Municipal wastewater Waste management Sewerage Systems Water supply Biogas-Projects Cost and fee calculation Plant operation Project management Turn-Key-Projects

4 Technologies for the biological carbon and nitrogen removal Basics Activated sludge system Sedimentation Sequency Batch Reactors Trickling filters Membrane Bioreactors Moving bed systems Nitrogen removal in partial streams

5 Application of the natural self regulation and cleaning processes from the nature to technical systems Trickling filter Activated sludge system

6 Aerobic processes Biochemical removal by microorganisms with enough free oxygen degradation of organic substances organic subtances + O 2 CO 2 + H 2 O nitrification (need sludge age < 6 days) NH 4 + O 2 NO 3 + H 2 O

7 Anoxic processes Biochemical removal by microorganisms without free but with bounded oxygen Denitrification organic compounds + NO 3 CO 2 + N 2 + H 2 O

8 Anaerobic processes Biochemical removal by microorganisms without any oxygen (no free oxygen and no NO 3 -N) Acidification organic compounds CO 2 + org. Säuren Degradation with methan production organic compounds CH 4 + CO 2

9 Growth-velocity [1/d] Monod-Relation Example for bacterias which grow in biomass-flocs Example for filamentous bacterias, active under lower concentrations Substrate-concentration

10 Vorgeschaltete Denitrifikation Pre-denitrification Inflow denitrification nitrification Effluent Final clarifier Internal recycle Recycle sludge

11 Efficiency of the denitrification as a function of the recycle ratio Recycle ratio

12 Pumps for the internal recycle

13 800,000 PE

14 DN N Rezi

15 WWTP -Gümmerwald, PE aqua consult - pre-denitrification and biological phosphorous removal - Gümmerwald

16 Kläranlage aqua Wilhelmshaven consult WWTP Wilhelmshaven Ingenieur ( GmbH PE)

17 Colakli WWTP Colakli/ Turkey, PE aqua-compact-system - with external aerobic stabilization -

18 WWTP Athen/ Greece, 4,5 mio PE aqua consult - denitrification, nitrification, Athen II biological phosphorous removal -

19 Athen I WWTP Athen/ Greece

20 aqua Athen consult III

21 BB Athen WWTP Athens Nitrification reactor, depth 9,50 m

22

23 Cooling of the air for the fine bubble aeration aqua consult Kühler

24 The world biggest archimedian srew

25 aqua consult

26 Cascade-denitrification with sepearted inflow to the single compartments Zulauf Inflow D1 N1 D2 N2 Dn Nn Rec 1 Rec 2 Rec n Rücklaufschlamm Recycle sludge D = Denitrifikation N = Nitrifikation Rec = interner Recycle Index= Nummer der Kassette D=Denitrification N=Nitrification Nachklärung Final clarifier Rec= internal recycle Ablauf Effluent Index = number of the cascade

27 Halberstadt aqua consult Biologie WWTP Halberstadt

28 Halberstadt aqua consult Biologie Required Volume: - 20 % WWTP Halberstadt

29 aqua Halberstadt consult Sedimentation

30 aqua NK consult Tartu

31 aqua NK Klarlauf consult

32 Final clarifiers, Kläranlage used aqua Rheda for consult - the Übersichtsbild research project

33

34

35 X TS,AN [g/l] aqua consult 0,025 Becken 1 Becken 2 0,020 DWA-A 131 design peak flow 0,015 0,010 0,005 0,

36 Optimization of the inlet structure

37

38 SBR Sequency Batch Reactor

39 Basics for the SBR-technology All functions in one reactor The functions of the reactor are controlled by time switch (feeding, aeration, mixing/ denitrification, sedimentation, outflow, sludge disposal, pause) Flexible system Storage needed

40 SBR-technology, WWTP Oschatz ( PE) aqua Oschatz consult SBR

41

42 SBR-Plant for the treatment aqua SBR-Anlage consult of slaughterhouse-wastewater

43 Membran Bioreactor MBR

44 Basics for the membrane treatment (MBR) The sludge production and the degradation rate does not differ from the classic activated sludge system Higher sludge concentration are possible (= less volume required) Treated wastewater according to EU bathing water requirements

45 Basics for the membrane treatment (MBR) Higher energy demand (for membrane cleaning, higher viscosity) An efficient pre-treatment is required (screens with 2 to 0,5 mm) Foam fighting should be considered (Foam-separation, chemical treatment) Main design parameter: Membrane Flux [m 3 /m 2 h]

46 Less oxygen transfer with increasing MLSS

47 Parameter Unit Conventional activated sludge plant (AS) Membrane Bioreactor (MBR) Filterable Solids mg/l COD mg/l < 30 N tot mg/l < 13 < 13 P tot mg/l 0,8 1,0 < 0,3 Microbiological quality Hygienically alarming Bathing water quality MLSS g/l < 5 < 20 Specific energy consumption kwh/m 3 0,2 0,4 0,7 1,5 Dohmann et al, 2002

48

49

50

51

52

53 Moving bed systems (MBBR)

54 Basics for the treatment with moving bed bioreactor systems (MBBR) Support medium for the growth of fixed microorganism Mineralic or syntetic support medium Diameter 2 to 50 mm Specific surfaces from 100 to m 2 /m 3

55 Basics for the treatment with moving bed bioreactor systems (MBBR) The oxygen level must be high enough to activate the inner zones of the biofilm The inflow needs in some cases the addition of polymer to bind the flocs

56 Usual design values for MBBR-systems Parameter Unit Specific carrier surface loading BOD 5 g/ m 2 d Nitrification g/ m 2 d 1,0 2,0 Denitrification g/ m 2 d 2,5

57 Cylindrical high-density polyethylene ring shaped carrier (AnoxKaldnes, K1)

58

59 Aerobic test plant Textile wastewater Kreenholm/ Narva/ Estonia

60 Biofilm system, pilot plant, feeding point aqua consult

61 Active biofilm aqua consult

62 Treatment of Paper production Wastewater with MBBR- technology

63 Trickling filter aqua Tropfkörper consult

64

65 - Energy saving system aqua consult for carbon removal and nitrification - combination with denitrification unefficient

66 Sludge stabilization - simultaneous aerobic - extern aerobic - extern anaerobic aqua consult Anaerobic Sludge Stabilization Weißenfels EW

67 Tönnies slaugherhouse Rheda-Wiedenbrück (capacity 30,000 pigs per day)

68 Flotation for slaughterhouse wastewater aqua consult 85 % COD Flotation removal - Flotate used for biogas production -

69 Components for the co-fermentation of flotate at the WWTP Rheda-Wiedenbrück Sludgewater treatment (PANDA) CHP-plant Anaerobic digester 2,8 MW el m m 3

70 Kläranlage Rheda - Übersichtsbild Technical Scale pilot for the sludge water treatment

71 Comparison of the nitrogen-removal over nitrate and over nitrite über Nitrat + NH NO NO N CSB/TKN: ~ 5, autotroph heterotroph über Nitrit + NH NO N CSB/TKN: ~ 3, autotroph heterotroph

72 Growth rates of nitrosomonas and nitrobacter as a function of the temperature according HUNIK (1993)

73

74 Deammonification with Pellets, DEMON technology, WWTP Heidelberg

75 Thank you for your kind attention

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