Die Freiheit der Meinung setzt voraus, dass man eine hat. Heinrich Heine ( )

Größe: px
Ab Seite anzeigen:

Download "Die Freiheit der Meinung setzt voraus, dass man eine hat. Heinrich Heine (1797 1856)"

Transkript

1 Scientific Programm

2

3 Die Freiheit der Meinung setzt voraus, dass man eine hat. Heinrich Heine ( )

4

5 Table of Contents Conference Programm 1 Abstracts of ral Presentations 4 Abstracts of Poster Presentations 29 List of Participants 58 Public transport Informations 62

6

7 Monday, :00-14:50: IL01 Prof. Dr. Matthias Tamm (TU Braunschweig) Synthesis and eactivity of Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes 14:50-15:15 P01 Matthias Kanthak (uhr-universität Bochum) Chelated uthenium Complexes of Functionalized Pentaarylcyclopentadienes 15:15-15:40 P02 Katharina Weitershaus (uprecht-karls-universität Heidelberg) Halfsandwich Titanium Complexes supported by 2-Aminopyrroline Ligands --- Coffee Break :15-16:40 P03 Manuela Gross (Julius-Maximilians-Universität Würzburg) Synthesis, Structure, and eactivity of Disila[2]metallocenophanes 16:40-17:05 P04 Daniel Weismann (TU Kaiserslautern) Substituted cyclopentadienyl and hexadienyl ligands in BiPh 3 -based TLE-reactions 17:05-17:30 P05 Thomas Glöge (TU Braunschweig) uthenium halfsandwich complexes with superbasic diimine ligands 17:30-18:30 eception/postersession Evening eception 1

8 Tuesday, :00-9:50 IL02 Prof. Dr. Didier Astruc (Université Bordeaux I) rrocene in nanosciences 9:50-10:15 P06 Daniel Franz (Johann-Wolfgang-Goethe-Universität Frankfurt) Synthesis of π-conjugated boron-containing polymers 10:15-10:40 P07 Barbara Enk (Universität Innsbruck) ew imino-functionalized fulvenes: versatile ambidentate ligands for novel ruthenocene complexes and olefin polymerization precatalysts --- Coffee Break :15-11:40 P08 Dr. Christian Färber (Universität Kassel) A stable crystalline -heterocyclic carbene with a 1,1 -ferrocenediyl backbone 11:40-12:05 P09 Markus Graser (Universität Innsbruck) Bis(imino) remote -heterocyclic carbene complexes 12:05-12:30 P10 Jiří Tauchman (Charles-University Prague) Phosphanylferrocene Conjugates with Amino Acids --- Lunch Break :00-14:50: IL03 Prof. Dr. Karl Kirchner (TU Wien) Transition Metal Pincer Complexes based on Aminophosphines Synthesis and Applications 14:50-15:15 P11 Tomáš Bobula (Charles-University Prague) Mo-Catalyzed Cross-Metathesis eaction of Propynylferrocene 15:15-15:40 P12 adine Langenscheidt-Dabringhausen (WTH Aachen) pen uthenocene: Just Another uthenium Precursor? --- Coffee Break :15-16:40 P13 Bram Pluijmaekers (heinische Friedrichs-Wilhelms-Universität Bonn) Dimerisation of bis(dimethylamino)acetylene on i(0) centers 16:40-17:05 P14 Dieter Schaarschmidt (TU Chemnitz) A Convenient Way to Functionalized Phosphinoferrocenes 17:05-17:30 P15 Wolfgang Bulla/ Dr. Hubert Jungbluth (Innospec Herne) 17:30-18:30 Postersession PLUTcen Industrial Production and Applications as Fuel Additive Evening Conference-Dinner 2

9 Wednesday, :00-9:50 IL04 Prof. Dr. Holger Butenschön (Leibniz-Universität Hannover) rrocene - A 3D Benzene 9:50-10:15 P16 Frank Pammer (TU Kaiserslautern) Dibenzo[c,g]fluorene: exploring the concept of aromaticity on complexes of an intrinsically chiral Cp-ligand 10:15-10:40 P17 Jessica Lemke (uhr-universität Bochum) Synthesis of ruthenium and rhodium imidazolium peptide conjugates --- Coffee Break :15-11:40 P18 Dr. Monika eger (Universität Stuttgart) emarkable Binding Capacity of [(dppf)cu] + for Weakly Coordinating π-acceptor Chelate Ligand 11:40-12:05 P19 Daniel ebler (Johannes-Gutenberg-Universität Mainz) ptical Detection of Anions and Small Biomolecules with rrocene Derivatives 12:05-12:30 P20 S. David Köster (uhr-universität Bochum) rrocene-peptide and -PA Bioconjugates via Click Chemistry 3

10 ral Contributions: IL P Invited Lectures ral Presentations IL01 Prof. Dr. Matthias Tamm (TU Braunschweig) P01 Matthias Kanthak (uhr-universität Bochum) P02 Katharina Weitershaus (uprecht-karls-universität Heidelberg) P03 Manuela Gross (Julius-Maximilians-Universität Würzburg) P04 Daniel Weismann (TU Kaiserslautern) P05 Thomas Glöge (TU Braunschweig) IL02 Prof. Dr. Didier Astruc (Université Bordeaux I) P06 Daniel Franz (Johann-Wolfgang-Goethe-Universität Frankfurt) P07 Barbara Enk (Universität Innsbruck) P08 Dr. Christian Färber (Universität Kassel) P09 Markus Graser (Universität Innsbruck) P10 Jiří Tauchman (Charles-University Prague) IL03 Prof. Dr. Karl Kirchner (TU Wien) P11 Tomáš Bobula (Charles-University Prague) P12 adine Langenscheidt-Dabringhausen (WTH Aachen) P13 Bram Pluijmaekers (heinische Friedrichs-Wilhelms-Universität Bonn) P14 Dieter Schaarschmidt (TU Chemnitz) P15 Wolfgang Bulla/ Dr. Hubert Jungbluth (Innospec Herne) IL04 Prof. Dr. Holger Butenschön (Leibniz-Universität Hannover) P16 Frank Pammer (TU Kaiserslautern) P17 Jessica Lemke (uhr-universität Bochum) P18 Dr. Monika eger (Universität Stuttgart) P19 Daniel ebler (Johannes-Gutenberg-Universität Mainz) P20 S. David Köster (uhr-universität Bochum) 4

11 Synthesis and eactivity of Functionalized Cycloheptatrienyl- Cyclopentadienyl Sandwich Complexes Matthias Tamm Institut für Anorganische und Analytische Chemie, Technische Universität Carolo-Wilhelmina, Hagenring 30, Braunschweig, Germany. In recent years, my group has been involved in the synthesis and reactivity of highly strained ansa-cht-cp complexes of type I, 1 which have been shown to be susceptible to strain release by undergoing ring-opening polymerization reactions (Figure 1). In addition, the bending of the two rings in these 16-electron complexes opens a potential vacancy at the titanium centre, which thereby becomes accessible to monodentate ligands such as C or isocyanides. 2 In contrast, the formation of thermally labile isocyanide, carbene and phosphine adducts can be observed for the zirconium and hafnium complexes II without resorting to the introduction of a bridging unit. 3 This reactivity prompted us to synthesize phosphorous-functionalized zirconium and hafnium Cht-Cp complexes of type III, since these systems can be expected to develop interesting secondary interactions involving the Zr or Hf metal atoms. 4 The resulting metallo-supramolecular chemistry will be the main focus of this presentation. Me Me Ti E P Me 2 E Ti +L -L Me 2 E Ti L n E =, Ge I L = C, C, P 3 M P 2 M = Zr, Hf M +L -L M L III II Figure 1. Cycloheptatrienyl-cyclopentadienyl group 4 complexes. eferences 1. M. Tamm, Chem. Commun. 2008, (a) M. Tamm, A. Kunst, T. Bannenberg, E. Herdtweck, P. rsch, C. J. Elsevier, J. M. Ernsting, Angew. Chem. Int. Ed. 2004, 43, (b) M. Tamm, A. Kunst, E. Herdtweck, Chem. Commun. 2005, (c) M. Tamm, A. Kunst, T. Bannenberg, S. andoll, P. G. Jones, rganometallics 2007, 26, (a) M. Tamm, A. Kunst, T. Bannenberg, E. Herdtweck,. Schmid, rganometallics 2005, 24, (b). J. Baker, T. Bannenberg, A. Kunst, S. andoll, M. Tamm, Inorg. Chim. Acta 2006, 359, S. Büschel, A.-K. Jungton, T. Bannenberg, S. andoll, C. G. Hrib, P. G. Jones, M. Tamm, Chem. Eur. J. 2009, in press. 5

12 Chelated uthenium Complexes of Functionalized Pentaarylcyclopentadienes M. Kanthak, a A. Aniol, a I. M. ppel, b G. Dyker* a a uhr-universität Bochum, Faculty of Chemistry and Biochemistry, rganic Chemistry II, Universitätsstr. 150, Bochum, Germany. b uhr-universität Bochum, Faculty of Chemistry and Biochemistry, Analytical Chemistry, Universitätsstr. 150, Bochum, Although the synthesis of cyclopentadienyl complexes with pendant donor groups has been a well established research field, 1 corresponding compounds with pentaphenylated cyclopentadienes are unknown. We have synthesized water- and air-stable ruthenium complexes with various chelating pentaarylcyclopentadiene ligands. Figure 1: Synthesis of ruthenium complexes 3, a,a : 1. u 3 (C) 12, 2. CHCl 3, b: hν The pendant coordination site is located at the ortho-position of one phenyl group. In general, the reaction 2 of the cyclopentadiene 1 with u 3 (C) 12 and chloroform (Figure 1) directly results in chelated complexes 3. Alternatively, irradiation of monodentate complex 2 leads to decarbonylation followed by an intramolecular coordination of the pendant group. The coordination establishes the ruthenium atom as a stable center of chirality. Most interestingly, only one possible diastereomer is detected for 3c and 3d, if the pendant donor is an enantiopure oxazoline. We are currently investigating scopes and limitations of enantioselective catalysis with these chiral ruthenium complexes. eferences 1. (a) U. emeling, Chem. ev. 2000, 100, (b) H. Butenschön, Chem. ev. 2000, 100, (c) P. Jutzi, T. edeker, Eur. J. Inorg. Chem. 1998, B. Martín-Matute, M. Edin, K Bogár, F. B. Kaynak, J.-E. Bäckvall, J. Am. Chem. Soc. 2005, 127,

13 Halfsandwich Titanium Complexes supported by 2-Aminopyrroline Ligands Katharina Weitershaus, a Hubert Wadepohl, a and Lutz H. Gade* a a Anorganisch-Chemisches Institut, Universität Heidelberg, Im euenheimer ld 270, Heidelberg, Germany Transition metal hydrazinediido compounds are of considerable interest with regard to the biological and synthetic fixation of molecular nitrogen. 1 ur investigations have focused on hydrazinediido complexes of group 4 elements whose chemistry is underdeveloped at this stage. n the other hand the chemistry of related imido compounds towards unsaturated molecules and their applications in hydroamination catalysis is well established. The work of our group 2 and others 3 has shown that group 4 complexes are on the one hand capable of - bond cleavage and on the other hand have the ability to perform [2+2] cycloaddition reactions. In 2002 dom reported the use of terminal hydrazinediido complexes in catalytic hydrohyrazination 4 and iminohydrazination 5 reactions of alkynes. The isolation of catalytic intermediates and the predictability of the behavior of hydrazinediido ligands towards unsaturated molecules remain elusive. In order to achieve this objective, it is important to further our knowledge on the reactivity of hydrazinediido compounds. A series of halfsandwich titanium hydrazinediido complexes, supported by 2-aminopyrroline ligands, 6 have been synthesised and characterised. The complexes were prepared by imido exchange reaction 7 from the corresponding imido complexes reported previously. Their behaviour towards unsaturated molecules such as thiocyanates, isothiocyanates, azides, alkynes and allenes was studied in stoichiometric reactions and the products were characterised spectroscopically and by X-ray diffraction. Furthermore we also tested our hydrazinediido complexes in catalytic hydrohydrazination reactions of terminal alkynes where a high selectivity towards the Markovnikoff product and a considerable reactivity even at room temperature was observed. eferences 1... Schrock, Acc. Chem. es., 2005, 38, H. Herrmann, J. Llorett, H. Waddepohl, L. H. Gade, Angew. Chem. Int. Ed., 2007, 46, P. J. Walsh, M. J. Carney,. G. Bergman, JACS, 1991, 113, 6343; J. D. Selby, C. D. Manley, M. liz, A. D. Schwarz, E. Clot, P. Mountford, Chem Commun, 2007, C. Cao, Y. Shi, A. L. dom, rg. Lett., 2002, 4, s. Banerjee, Y. Shi, C. Cao, A. L. dom, J rganomet. Chem., 2005, 690, 5066; S. Banerjee, A. L. dom, rganometallics, 2006, 25, B. D. Ward, H. isler, K. Weitershaus, S- Bellemin-Laponnaz, H. Wadepohl, L. H. Gade, Inorg. Chem., 2006, 45, A. J. Blake, P. E. Collier, S. C. Dunn, W.-S. Li, P. Mountford,. V. Shishikin, J. Chem. Soc, Dalton Trans., 1997,

14 Synthesis, Structure, and eactivity of Disila[2]metallocenophanes M. Gross, K. adacki, and H. Braunschweig* Julius-Maximilians-Universität Würzburg, Faculty of Chemistry and Pharmacy, Department of Inorganic Chemistry, Am Hubland, 97074, Würzburg, Germany. Disila[2]metallocenophanes of groups 4 and 8 are already known and their reactivity has been thoroughly investigated. We, however, succeeded in the preparation of some new disila-brigded ansa-complexes by lithiation of 1,2-bis(cyclopentadienyl)-1,1,2,2-tetramethyldisilane and subsequent reaction with suitable metalhalides. 1 Me Me Me Me 1) 2 BuLi 2) x Me Me Me Me ML n x = MoCl 5 / a[bh 4 ] [WCl 4 (dme)] / Li[AlH 4 ] [CoBr 2 (dme)] [icl 2 (dme)] ML n = MoH 2 WH 2 Co i + Isomere f particular interest is the reactivity of the E E-bond of [2]metallocenophanes (E = B, ). Some homogenous and heterogenous catalyzed insertions of unsaturated organic substrates as well as oxidative addition to late transition metals have been reported. 2 ecently, we accomplished for the first time an intramolecular reaction under cleavage of the -bond. The ansa-molybdenocenedihydride reacts photochemically under elimination of hydrogen resulting in a twofold bridged disila[1],[1]molybdenocenophane. Furthermore, the synthesized ansa-complexes reveal a manifold and unexpected reactivity. Me Me Me Me Mo H H hν -H 2 Me Me Me Me Mo Me Me Me Me Mo eferences 1. (a) H. Braunschweig, M. Gross, K. adacki, rganometallics 2007, 26, (b) H. Braunschweig, F. Breher, M. Kaupp, M. Gross, T. Kupfer, D. ied, K. adacki, S. Schinzel, rganometallics 2008, 27, (c) H. Braunschweig, M. Gross, K. adacki, Angew. Chem. Int. Ed. 2008, 47, (a) H. Braunschweig, T. Kupfer, M. Lutz, K. adacki, F. Seeler,. gritz, Angew. Chem. Int. Ed. 2006, 45, (b) H. Braunschweig, T. Kupfer, rganometallics 2007, 26, (c) H. Braunschweig, T. Kupfer, J. Am. Chem. Soc. 2008, 130, (d) H. Braunschweig, M. Kaupp, C. J. Adams, T. Kupfer, K. adacki, S. Schinzel, J. Am. Chem. Soc. 2008, 130,

15 Substituted cyclopentadienyl and hexadienyl ligands in BiPh 3 -based TLE-reactions D. Weismann, 1,2 A. Verma, 1 M. Gillett-Kunnath, 1 G. B. Deacon, 3 H. tzmann, 2 K. uhlandt-senge 1 1 Dept. of Chemistry, CST 1-014, Stracuse, Y Fachbereich Chemie, TU Kaiserslautern, Germany 3 School of Chemistry, Monash University, Clayton, 3800 Australia Based on our recent work on using edox Transmetallation/ Ligand Exchange (TLE) using BiPh 3 for the synthesis of alkaline earth metal amides 1, we here demonstrate the potential of TLE for the synthesis of organoalkaline earth complexes. By employing cyclopentadiene ligands displaying different degrees of steric bulk in addition to several related ligand systems we demonstrate the influence of ligand size in the preparation of the target compounds. We will also discuss the preparation of alkaline earth metal hexadienyl complexes by employing similar methodology. 1) Gillett-Kunnath, M. M., MacLellan, J. G., Forsyth, C. M., Andrews, P. C., Deacon, G. B., uhlandt-senge, K. BiPh 3 A convenient synthon for heavy alkaline earth metal amides. Chem. Commun. 2008, Advance article on the web B806948D. 9

16 uthenium halfsandwich complexes with superbasic diimine ligands T. Glöge, Dejan Petrovic, and M. Tamm* a a Technische Universität Braunschweig,Fakultät für Lebenswissenschaften, Institut für Anorganische und Analytische Chemie, Hagenring 30, 38106, Braunschweig, Germany. The chemistry of imidazolin-2-iminato ligands has been well established in important areas as alkyne metathesis 1 or olefin polymerisation 2. The coupling of two iminato moieties via an ethane-bridge leads to neutral, though very electron rich diimine ligands 3. They can donate between four and eight electrons depending on the electron demand of the coordinated metal fragment (compare structures 1a and 1b). 1a 1b Figure 1. Diimine ligand ( = Me, ipr). Three ruthenium halfsandwich moieties have been used to exemplify the characteristics of this ligand type. Figure 2 shows two arbitrary examples from this class of compounds with pseudo-trigonal or piano-stool coordination at the ruthenium centre. The ruthenium-nitrogen bond lengths are around 2.0Å long and therefore very short for neutral nitrogen donor atoms. Me Me Me u Me Cl Me u Cl 2 3 Figure 2. uthenium diimine complexes ( = Me, ipr). Cl These complexes have been studied concerning the addition of C or isocyanide ligands to provide further information about their activity 4. The ruthenium compounds have been shown to be catalytically active in direct hydrogenation and reductive transfer hydrogenation of carbonyl compounds. 1. M. Tamm, S. Beer, C. G. Hrib, P. G. Jones, K. Brandhorst, J. Grunenberg, Angew. Chem. Int. Ed. 2007, 46, M. Tamm, S. andoll, E. Herdtweck,. Kleigrewe, G. Kehr, G. Erker, B. ieger, Dalton Trans. 2006, milar ligands:. Kuhn, et.al. Z. aturforsch. 1998, 53, 997; G. Henkel, et. al., Eur. J. rg. Chem. 2005, 4879; 3. M. Tamm, D. Petrovic, T. Bannenberg, S. andoll, P. G. Jones, Dalton Trans. 2007, M. Tamm, D. Petrovic, T. Glöge, T. Bannenberg, C. G. Hrib, S. andoll, P. G. Jones, Eur. J. Inorg. Chem. 2007,

17 rrocene in nanosciences Didier Astruc, ISM, Université Bordeaux 1, Talence Cedex,, France In this lecture, the assembly of dendrimers and nanoparticles of various sizes and generations containing ferrocenyl termini will be illustrated. Supramolecular and nanoscience aspects involve redox functions 1 leading to applications in redox catalysis, 2 molecular recognition and electrochemical sensing (Figure 1). 3 S S S S S S S S S S S S S S S S S S S S ATP Sensing H 2 P P P CH 2 H H H H Figure 1. Au-nanoparticle-centered ferrocenyl dendrimer that senses ATP eferences 1. (a) C. rnelas, C. Belin, J. uiz, D. Astruc, J. Am. Chem. Soc. 2009, 11, DI: / ja ; (b) D. Astruc, C. rnelas, J. uiz, Acc. Chem. es. 2008, 41 (7) D. Astruc, rganometallic Chemistry and Catalysis, Springer, Heidelberg, 2007, Ch (a) M.-C. Daniel, J. uiz, D. Astruc, J. Am. Chem. Soc., 2003, 125, ; (b) M.-C. Daniel, J. uiz, S. late, J.-C. Blais, D. Astruc, J. Am. Chem. Soc., 2003, 125,

18 Synthesis of π-conjugated boron-containing polymers D. Franz a, U. D. Eckensberger a, A. Lorbach a, M. Scheibitz b, M. Wagner a a Goethe-Universität Frankfurt, Faculty of Chemistry, Department of Inorganic and Analytical Chemistry, Max-von-Laue-Straße 7, 60438, Frankfurt, Germany. b Former group member, now BASF AG. ur group spends effort on the synthesis of arylhydroboranes and arylbromoboranes with one or several boron moieties as precursors for boron-containing polymers. This led to the discovery of the condensation reaction of ferrocenylboranes by liberation of B 2 H 6 (borane coupling). 1 After abstraction of a hydride ion from lithium ferrocenyltrihydroborate the formed ferrocenylborane undergoes borane coupling to Fc 2 BH if not trapped as stable Lewis acidbase adduct. 2a Extension of this reactivity to the ditopic ferrocenylborane 1,1 -fc(bh 2 SMe 2 ) 2 yielded the corresponding polyferrocenylborane (compare Figure 1 A). 2a,2b 9,10-dihydro-9,10-diboraanthracene (DBA), which cannot liberate diborane by the condensation reaction pathway, was successfully applied in the hydroboration polymerization with diynes (Figure 1 B). 3a,3b The reaction of aryldibromoboranes with triethylsilane in the absence of an electron donor yielded the corresponding diarylbromoboranes accompanied by the liberation of B 2 H 6 and the formation of triethylbromosilane. 4a This reaction principle of hydrosilane-mediated coupling between arylbromoboranes was transferred to the dinuclear arylbromoboranes containing two boron moieties and the corresponding polyarylbromoboranes were obtained. 4b A n H 2 B Ar BH Ar 2 - n/2 B 2 H 6 B H n B n H B B H n Ar B B Ar n Figure 1: Polymerization reactions of dinuclear arylboranes. A: borane coupling (Ar = fc, ph), B: Hydroboration polymerization of 9,10-dihydro-9,10-diboraanthracene. eferences: 1. J. B. Heilmann, M. Scheibitz, Y. Qin, A. Sundararaman, F. Jäkle, M. Bolte, H.-W- Lerner, M. C. Holthausen, M. Wagner, Angew. Chem. Int. Ed. 2006, 45, (a) M. Scheibitz, J. W. Bats, M. Bolte, H.-W. Lerner, M. Wagner, rganometallics 2004, 23, (b) M. Scheibitz, Dissertation JWG Universität Frankfurt (a) A. Lorbach, Diploma Thesis Goethe-Universität Frankfurt (b) M. Wagner et al, paper in preparation 4. (a) U. D. Eckensberger, Diploma Thesis JWG Universität Frankfurt 2006 (b) M. Wagner et al, paper in preparation 12

19 ew imino-functionalized fulvenes: versatile ambidentate ligands for novel ruthenocene complexes and olefin polymerization precatalysts B. Enk, a H. Kopacka, a K. Wurst, a T. Müller, b and B. Bildstein* a a University of Innsbruck, Faculty of Chemistry and Pharmacy; Institute of General, Inorganic and Theoretical Chemistry; Innrain 52a, A-6020 Innsbruck, Austria. b University of Innsbruck, Faculty of Chemistry and Pharmacy; Institute of rganic Chemistry; Innrain 52a, A-6020 Innsbruck, Austria. In general, in organometallic and coordination chemistry the reactivity and catalytic applications of metal complexes are controlled by the stereoelectronic properties of the ligand sphere. In this contribution, we present new [,]/[,]/Cp ligand families based on novel imino-functionalized fulvenes and their coordination chemistry: synthesis: modular, 1- or 2-step, starting from easily available synthons; structure: planar, conjugated, tautomeric, with tunable steric shielding and Lewis-basicity; variability: homo- or heteroleptic [,]/[,] chelate ligand systems with 1,2- or 1,3- substitution pattern and/or 1,2- or 1,3-functionalized cyclopentadienide precursors; reactivity: ambidentate ligands depending on the hard/soft character of the metal fragments: anionic ligands for κ 2 -[,]/[,]-7-ring metal chelates, neutral/anionic 1,2-/1,3-substituted (planar-chiral) ruthenocene-[,]/[,]-ligands; catalytic applications: new ligand families for olefin polymerization precatalysts of early to late transition metals. 13

20 A stable crystalline -heterocyclic carbene with a 1,1 -ferrocenediyl backbone C. Färber, a C. Bruhn, b and U. emeling* c a University of Kassel, Department of Chemistry, Heinrich-Plett-Staße 40, 34132, Kassel, Germany. b University of Kassel, Department of Chemistry, Heinrich-Plett-Straße, 34132, Kassel, Germany. c University of Kassel, Department of Chemistry, Heinrich-Plett-Straße 40, 34132, Kassel, Germany. -heterocyclic carbenes (HCs) are exceptionally important and versatile ligands suitable for a wide range of applications. 1 Even for the most widely investigated HCs (i. e. those containing a 5-membered ring system with no further heteroatoms), the electronic properties are still not fully understood. This is even more the case for HCs ring sizes other than 5 and/or heteroatoms in the backbone. 2 C Figure 1. x-membered HC with a 1,1 -ferrocenediyl backbone We are interested in HCs which contain a 1,1 -ferrocenediyl backbone, which would render this system redox-active (figure 1). We envisage that such HCs would be particularly suitable for investigations which use electrochemical methods to probe and switch the electronic properties of these ligands. First examples of metal complexes containing such HCs were published previously by Bielawski. 3 C h Cl C Mo C C C Figure 2. Free carbene 1 and its metal complexes 2 and 3 We present the synthesis of a new stable 2-adamantyl substituted carbene 1 with a redoxactive ferrocene-based backbone. It was characterised by X-ray crystallography. The carbene was utilised as a ligand in preparation of expected and unexpected metal complexes 2 and 3 (figure 2). 4 Support of this work by the Deutsche Forschungsgemeinschaft is gratefully acknowledged. eferences 1. S. P. olan (ed.), -Heterocyclic Carbenes in Synthesis, Wiley-VCH, Weinheim, See, for example: C. C. Scarborough, M. J. W. Grady, I. A. Guzei, B. A. Gandhi, E. E. Bunel, S. S. Stahl, Angew. Chem. Int. Ed. 2005, 44, D. M. Khramov, E. L. osen, V. M. Lynch, C. W. Bielawski, Angew. Chem., Int. Ed., 2008, 47, U. emeling, C. Bruhn, C. Färber, Chem. Commun., 2009, 98 14

21 Bis(imino) remote -heterocyclic carbene complexes M. Graser, a A. Solchinger, a H. Kopacka, a K. Wurst, a T. Müller, b and B. Bildstein* a a University of Innsbruck, Faculty of Chemistry and Pharmacy; Institute of General, Inorganic and Theoretical Chemistry; Innrain 52a, A-6020 Innsbruck, Austria. b University of Innsbruck, Faculty of Chemistry and Pharmacy; Institute of rganic Chemistry; Innrain 52a, A-6020 Innsbruck, Austria. During the past ten years -heterocyclic carbenes (HCs) have been very successfully implemented as novel steering ligands in catalytically active metal complexes, most notably for olefin metathesis and carbon-carbon cross-coupling reactions. In general, almost all of these ligand frameworks are based on imidazole or other azole heterocyclic cores where the carbene carbon is located in the "normal" position between the two nitrogen atoms. In contrast, "abnormal" HCs with the carbene carbon in a remote position, so-called "rhcs", are much less known. In this contribution, we report on new tridentate bis(imino)pyridylidene rhcs as new ligands of late transition metal centers for potential applications in homogenous and/or heterogenous catalysis, e.g. olefin polymerization. Conceptually, these tridentate [,C,] ligand systems were designed in close electronic and steric analogy to Brookhart/Gibson's very successful bis(imino)pyridine [,,]Cl 2 olefin polymerization catalysts. Synthetically, the key precursors of bis(imino)pyridylidene rhcs are accessible by a modular protocol, thereby allowing convenient steric modulation of the peripheral -aryl substituents. More demanding but nevertheless manageable is the formation of the "free" rhcs from their conjugated acids by interaction with suitable bases. Finally, transmetalation and/or complex formation with various transition metal halides gives access to [,C,] complexes. Spectroscopic results and single crystal X-ray structures as well as potential catalytic applications will be presented and discussed. 15

22 Phosphanylferrocene Conjugates with Amino Acids J. Tauchman, a and P. Štěpnička* a a Charles University in Prague, Faculty of Science, Department of Inorganic Chemistry, Hlavova 2030, , Prague, Czech epublic. In recent years, tremendous progress has been made in the design of new chiral ligands with phosphanylferrocene unit for the development of highly efficient metal-catalyzed asymmetric transformations. 1 We have recently reported the utilisation of several (phosphanyl)ferrocenecarboxylic acids and related amides combining planar and central chirality as ligands in enantioselective palladium-catalysed allylic alkylation reaction. 2,3 With this contribution, we report on the synthesis of new chiral phosphanylferrocene amides possessing amino acid pendant groups (types 1 and 2 in Figure 1). PPh2 C 2 H PPh2 PPh2 C 2 H C 2 H Hdpf (Sp)-HL (p)-hl H C PPh2 C H C Me C PPh2 Me PPh2 C H C Me 1 = ()-Me, (S)-Me, ()-CHMe2, (S)-CHMe2, ()-CH2Ph, (S)-CH2Ph 2 = H, ( )-Me, (S)-Me, ()-CHMe2, (S)-CHMe2, ()-CH2Ph, (S)-CH2Ph Figure 1. 2 = (S)-Me Synthetic methodology allowed for the preparation of structurally related compounds in which planar and central chirality are independently varied. Thus accessible families of closely related ligands enabled us to evaluate the influence of individual molecular parts on the course of asymmetric allylic alkylation of racemic (E)-1,3-diphenylprop-2-en-1-yl acetate with malonate esters. 4 eferences 1. (a) T. Hayashi: Asymmetric Catalysis with Chiral rrocenylphosphine Ligands in rrocenes; A. Togni, T. Hayashi, Eds.; VCH: Weinheim, Germany, 1995; pp (b) Part 1 rrocene Ligands in rrocenes: Ligands, Materials and Biomolecules; P. Štěpnička, Ed.; Wiley: Chichester, UK, 2008; pp M. Lamač, I. Císařová, P. Štěpnička, Eur. J. Inorg. Chem. 2007, M. Lamač, J. Tauchman, I. Císařová, P. Štěpnička, rganometallics 2007, 26, (a) B. M. Trost, D. L. Van Vranken, Chem. ev. 1996, 96, (b) B. M. Trost, M. L. Crawley, Chem. ev. 2003, 103,

23 Transition Metal Pincer Complexes based on Aminophosphines Synthesis and Applications Karl Kirchner* and David Benito-Garagorri Institute of Applied Synthetic Chemistry and Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Wien. ne of the ways of modifying and controlling the properties of transition metal complexes is the use of so-called pincer ligands. This class of tridentate ligands has found numerous applications in various areas of chemistry, including catalysis, due to their combination of stability, activity and variability. Focusing on pincer ligands featuring phosphines as donor groups, the lack of a general method for the preparation of both neutral (PP) and anionic (PCP) pincer ligands using similar precursor compounds as well as the difficulty of introducing chirality into the structure of pincer ligands prompted us to investigate the use of amines as spacers between the aromatic ring and the phosphines. By introducing aminophosphine and phosphoramidite moieties into their structure, the synthesis of both PP and PCP ligands can be achieved via simple condensation reactions. This has resulted in the preparation of a range of new pincer complexes, including various iron complexes which exhibit unusual properties both in the solid state and in solution. The use of some of these complexes as catalysts in different C-C coupling reactions has also been investigated. This lecture presents an overview of ongoing research in the field of aminophosphine-based pincer complexes with emphasis on iron chemistry. eferences 1. Benito-Garagorri, D.; Kirchner, K. Acc. Chem. es. 2008, 41, Benito-Garagorri, D., Puchberger, M.; Mereiter, K.; Kirchner, K. Angew. Chem., Int. Ed., 2008, 47,

24 Mo-Catalyzed Cross-Metathesis eaction of Propynylferrocene T. Bobula, a J. Hudlický, a P. ovák, a. Gyepes, b P. Štěpnička,* b and M. Kotora* a,c a Department of rganic and uclear Chemistry, Faculty of Science, Charles University, Hlavova 8, Praha 2, Czech epublic. b Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 8, Praha 2, Czech epublic. c Institute of rganic Chemistry and Biochemistry, Academy of Sciences of the Czech epublic, Flemingovo nám. 2, Praha 6, Czech epublic.. We reported that catalysts formed in situ from [Mo(C)6] and halophenols in dichloromethane efficiently promote homo-metathesis reactions of (prop-1-yn-1-yl)ferrocene 1 to bis(ferrocenyl)ethyne. 1 The same catalytic system was found to be also active in crossmetathesis reactions of (prop-1-yn-1-yl)ferrocene 1 with various functionalized alkynes 2. 2 The corresponding alkynylferrocenes were obtained with good selectivity and yields. ptimization of the reaction conditions by changing the phenol component has been carried out, revealing a critical influence of the phenol structure on the reaction yield. 1 Me + Me 2x [Mo(C) 6] (20 mol%) halophenol (1 equiv.) toluene, 120 C 3x x = a, = 4-MeC 6 H 4 - b, = 4-MeC 6 H 4 - c, = C 6 H 5 - d, = 4-PhC 6 H 4 - e, = 4-MeCC 6 H 4 - f, = 4-CF 3 C 6 H 4 - g, = 4-CC 6 H 4 - h, = n-c 6 H 13 - i, = AcCH 2 CH 2 - Figure 1. Cross-metathesis of Propynylferrocene 1 with Alkynes 2. The structures of selected compounds were determined by single-crystal X-ray diffraction, and the results (particularly the crystal packing) were correlated with DFT calculations. In addition, the series of alkynes FcC CC 6 H 4 C-X-4 3 (Fc = ferrocenyl) differing by the substituent X was studied by electrochemical methods, manifesting a good correlation between the redox potential of the ferrocene/ferrocenium couple and the Hammett σ p constants of the remote substituents X. eferences 1. D. ečas, M. Kotora, P. Štěpnička, Collect. Czech. Chem. Commun. 2003, 68, T. Bobula, J. Hudlický, P. ovák,. Gyepes, P. Štěpnička, M. Kotora, Eur. J. Inorg. Chem. 2008,

Chelatisierende Koordination von Glucopyranose an ein Metallzentrum.

Chelatisierende Koordination von Glucopyranose an ein Metallzentrum. Lars Jessen Dissertation 3 Zusammenfassung Ziel der vorliegenden Arbeit war, die Möglichkeit der Koordination von Kohlenhydratbausteinen, insbesondere von Glucopyranosen, als Diolatoliganden an (IV)- und

Mehr

Chiral Ferrocenyl Amidines as Modular Ligands for. Applications in Asymmetric Catalysis

Chiral Ferrocenyl Amidines as Modular Ligands for. Applications in Asymmetric Catalysis Dissertation ET o. 18199 Chiral rrocenyl Amidines as Modular Ligands for Applications in Asymmetric Catalysis A Dissertation Submitted to the SWISS FEDERAL ISTITUTE OF TECOLOGY ZURIC For the Degree of

Mehr

WP2. Communication and Dissemination. Wirtschafts- und Wissenschaftsförderung im Freistaat Thüringen

WP2. Communication and Dissemination. Wirtschafts- und Wissenschaftsförderung im Freistaat Thüringen WP2 Communication and Dissemination Europa Programm Center Im Freistaat Thüringen In Trägerschaft des TIAW e. V. 1 GOALS for WP2: Knowledge information about CHAMPIONS and its content Direct communication

Mehr

Titanium The heaviest light metal

Titanium The heaviest light metal Titanium The heaviest light metal Dan Snitkovsky Uniweld Israel FRONIUS International GmbH Buxbaumstr. 2 4600 Wels Titanium The heaviest light metal 0,5g/cm³ 4,5g/cm³ Heavy metal Lithium - light metal

Mehr

CHAMPIONS Communication and Dissemination

CHAMPIONS Communication and Dissemination CHAMPIONS Communication and Dissemination Europa Programm Center Im Freistaat Thüringen In Trägerschaft des TIAW e. V. 1 CENTRAL EUROPE PROGRAMME CENTRAL EUROPE PROGRAMME -ist als größtes Aufbauprogramm

Mehr

Customer-specific software for autonomous driving and driver assistance (ADAS)

Customer-specific software for autonomous driving and driver assistance (ADAS) This press release is approved for publication. Press Release Chemnitz, February 6 th, 2014 Customer-specific software for autonomous driving and driver assistance (ADAS) With the new product line Baselabs

Mehr

Exercise (Part XI) Anastasia Mochalova, Lehrstuhl für ABWL und Wirtschaftsinformatik, Kath. Universität Eichstätt-Ingolstadt 1

Exercise (Part XI) Anastasia Mochalova, Lehrstuhl für ABWL und Wirtschaftsinformatik, Kath. Universität Eichstätt-Ingolstadt 1 Exercise (Part XI) Notes: The exercise is based on Microsoft Dynamics CRM Online. For all screenshots: Copyright Microsoft Corporation. The sign ## is you personal number to be used in all exercises. All

Mehr

Efficient Design Space Exploration for Embedded Systems

Efficient Design Space Exploration for Embedded Systems Diss. ETH No. 16589 Efficient Design Space Exploration for Embedded Systems A dissertation submitted to the SWISS FEDERAL INSTITUTE OF TECHNOLOGY ZURICH for the degree of Doctor of Sciences presented by

Mehr

Mitglied der Leibniz-Gemeinschaft

Mitglied der Leibniz-Gemeinschaft Methods of research into dictionary use: online questionnaires Annette Klosa (Institut für Deutsche Sprache, Mannheim) 5. Arbeitstreffen Netzwerk Internetlexikografie, Leiden, 25./26. März 2013 Content

Mehr

Franke & Bornberg award AachenMünchener private annuity insurance schemes top grades

Franke & Bornberg award AachenMünchener private annuity insurance schemes top grades Franke & Bornberg award private annuity insurance schemes top grades Press Release, December 22, 2009 WUNSCHPOLICE STRATEGIE No. 1 gets best possible grade FFF ( Excellent ) WUNSCHPOLICE conventional annuity

Mehr

aus Doktorarbeiten Anna Lena Birkmeyer Oktober 2016

aus Doktorarbeiten Anna Lena Birkmeyer Oktober 2016 aus Doktorarbeiten Anna Lena Birkmeyer Fachbereich Mathematik TU Kaiserslautern Oktober 2016 In der der Arbeit: The mathematical modeling and optimization of... is a wide field of research [4,15,19,35,61,62,66,76,86]

Mehr

Climate change and availability of water resources for Lima

Climate change and availability of water resources for Lima Climate change and availability of water resources for Lima András Bárdossy bardossy@iws.uni-stuttgart.de Lima Marzo 12. 2009 1 Engineers and the future Knowledge about Past Design for Future Lima Marzo

Mehr

ELBA2 ILIAS TOOLS AS SINGLE APPLICATIONS

ELBA2 ILIAS TOOLS AS SINGLE APPLICATIONS ELBA2 ILIAS TOOLS AS SINGLE APPLICATIONS An AAA/Switch cooperative project run by LET, ETH Zurich, and ilub, University of Bern Martin Studer, ilub, University of Bern Julia Kehl, LET, ETH Zurich 1 Contents

Mehr

Exercise (Part II) Anastasia Mochalova, Lehrstuhl für ABWL und Wirtschaftsinformatik, Kath. Universität Eichstätt-Ingolstadt 1

Exercise (Part II) Anastasia Mochalova, Lehrstuhl für ABWL und Wirtschaftsinformatik, Kath. Universität Eichstätt-Ingolstadt 1 Exercise (Part II) Notes: The exercise is based on Microsoft Dynamics CRM Online. For all screenshots: Copyright Microsoft Corporation. The sign ## is you personal number to be used in all exercises. All

Mehr

1. General information... 2 2. Login... 2 3. Home... 3 4. Current applications... 3

1. General information... 2 2. Login... 2 3. Home... 3 4. Current applications... 3 User Manual for Marketing Authorisation and Lifecycle Management of Medicines Inhalt: User Manual for Marketing Authorisation and Lifecycle Management of Medicines... 1 1. General information... 2 2. Login...

Mehr

Pilot area B: Zeeland (B + NL) Pilot area C: Terschelling and Northern Fryslan (NL) Pilot area D: Borkum (D)

Pilot area B: Zeeland (B + NL) Pilot area C: Terschelling and Northern Fryslan (NL) Pilot area D: Borkum (D) Pilot area A: Belgische Middenkust, (B) Pilot area B: Zeeland (B + NL) Pilot area C: Terschelling and Northern Fryslan (NL) Pilot area D: Borkum (D) Pilot area E: Schleswig and Sdr. Jylland (D + DK) Pilot

Mehr

Lehrstuhl für Allgemeine BWL Strategisches und Internationales Management Prof. Dr. Mike Geppert Carl-Zeiß-Str. 3 07743 Jena

Lehrstuhl für Allgemeine BWL Strategisches und Internationales Management Prof. Dr. Mike Geppert Carl-Zeiß-Str. 3 07743 Jena Lehrstuhl für Allgemeine BWL Strategisches und Internationales Management Prof. Dr. Mike Geppert Carl-Zeiß-Str. 3 07743 Jena http://www.im.uni-jena.de Contents I. Learning Objectives II. III. IV. Recap

Mehr

Extended Ordered Paired Comparison Models An Application to the Data from Bundesliga Season 2013/14

Extended Ordered Paired Comparison Models An Application to the Data from Bundesliga Season 2013/14 Etended Ordered Paired Comparison Models An Application to the Data from Bundesliga Season 2013/14 Gerhard Tutz & Gunther Schauberger Ludwig-Maimilians-Universität München Akademiestraße 1, 80799 München

Mehr

aqpa Vereinstreffen 15. Okt. 2014, Wien

aqpa Vereinstreffen 15. Okt. 2014, Wien aqpa Vereinstreffen 15. Okt. 2014, Wien EU-GMP-Richtlinie Part II Basic Requirements for Active Substances used as Starting Materials Dr. Markus Thiel Roche Austria GmbH History ICH Richtlinie Q7 Nov.

Mehr

STRATEGISCHES BETEILIGUNGSCONTROLLING BEI KOMMUNALEN UNTERNEHMEN DER FFENTLICHE ZWECK ALS RICHTSCHNUR FR EIN ZIELGERICHTETE

STRATEGISCHES BETEILIGUNGSCONTROLLING BEI KOMMUNALEN UNTERNEHMEN DER FFENTLICHE ZWECK ALS RICHTSCHNUR FR EIN ZIELGERICHTETE BETEILIGUNGSCONTROLLING BEI KOMMUNALEN UNTERNEHMEN DER FFENTLICHE ZWECK ALS RICHTSCHNUR FR EIN ZIELGERICHTETE PDF-SBBKUDFZARFEZ41-APOM3 123 Page File Size 5,348 KB 3 Feb, 2002 TABLE OF CONTENT Introduction

Mehr

STRATEGISCHES BETEILIGUNGSCONTROLLING BEI KOMMUNALEN UNTERNEHMEN DER FFENTLICHE ZWECK ALS RICHTSCHNUR FR EIN ZIELGERICHTETE

STRATEGISCHES BETEILIGUNGSCONTROLLING BEI KOMMUNALEN UNTERNEHMEN DER FFENTLICHE ZWECK ALS RICHTSCHNUR FR EIN ZIELGERICHTETE BETEILIGUNGSCONTROLLING BEI KOMMUNALEN UNTERNEHMEN DER FFENTLICHE ZWECK ALS RICHTSCHNUR FR EIN ZIELGERICHTETE PDF-SBBKUDFZARFEZ41-SEOM3 123 Page File Size 5,348 KB 3 Feb, 2002 TABLE OF CONTENT Introduction

Mehr

FIVNAT-CH. Annual report 2002

FIVNAT-CH. Annual report 2002 FIVNAT-CH Schweizerische Gesellschaft für Reproduktionsmedizin Annual report 2002 Date of analysis 15.01.2004 Source: FileMaker Pro files FIVNAT_CYC.FP5 and FIVNAT_PAT.FP5 SUMMARY TABLE SUMMARY RESULTS

Mehr

VGM. VGM information. HAMBURG SÜD VGM WEB PORTAL - USER GUIDE June 2016

VGM. VGM information. HAMBURG SÜD VGM WEB PORTAL - USER GUIDE June 2016 Overview The Hamburg Süd VGM-Portal is an application which enables to submit VGM information directly to Hamburg Süd via our e-portal web page. You can choose to insert VGM information directly, or download

Mehr

Chemical heat storage using Na-leach

Chemical heat storage using Na-leach Hilfe2 Materials Science & Technology Chemical heat storage using Na-leach Robert Weber Empa, Material Science and Technology Building Technologies Laboratory CH 8600 Dübendorf Folie 1 Hilfe2 Diese Folie

Mehr

J RG IMMENDORFF STANDORT F R KRITIK MALEREI UND INSPIRATION ERSCHEINT ZUR AUSSTELLUNG IM MUSEUM LU

J RG IMMENDORFF STANDORT F R KRITIK MALEREI UND INSPIRATION ERSCHEINT ZUR AUSSTELLUNG IM MUSEUM LU J RG IMMENDORFF STANDORT F R KRITIK MALEREI UND INSPIRATION ERSCHEINT ZUR AUSSTELLUNG IM MUSEUM LU 8 Feb, 2016 JRISFRKMUIEZAIMLAPOM-PDF33-0 File 4,455 KB 96 Page If you want to possess a one-stop search

Mehr

Labour law and Consumer protection principles usage in non-state pension system

Labour law and Consumer protection principles usage in non-state pension system Labour law and Consumer protection principles usage in non-state pension system by Prof. Dr. Heinz-Dietrich Steinmeyer General Remarks In private non state pensions systems usually three actors Employer

Mehr

Stuart Chalk Evan Bolton

Stuart Chalk Evan Bolton Program of the Chemical Information Division Symposium: Symposium Organizers: : An Important Triple to Advance Science Stuart Chalk Evan Bolton March 16, 2016 9.35 a.m. 10:00 a.m. Room 25B - San Diego

Mehr

Large-Scale Mining and Retrieval of Visual Data in a Multimodal Context

Large-Scale Mining and Retrieval of Visual Data in a Multimodal Context Diss. ETH No. 18190 Large-Scale Mining and Retrieval of Visual Data in a Multimodal Context A dissertation submitted to the SWISS FEDERAL INSTITUTE OF TECHNOLOGY ZURICH for the degree of Doctor of Technical

Mehr

Using TerraSAR-X data for mapping of damages in forests caused by the pine sawfly (Dprion pini) Dr. Klaus MARTIN klaus.martin@slu-web.

Using TerraSAR-X data for mapping of damages in forests caused by the pine sawfly (Dprion pini) Dr. Klaus MARTIN klaus.martin@slu-web. Using TerraSAR-X data for mapping of damages in forests caused by the pine sawfly (Dprion pini) Dr. Klaus MARTIN klaus.martin@slu-web.de Damages caused by Diprion pini Endangered Pine Regions in Germany

Mehr

The poetry of school.

The poetry of school. International Week 2015 The poetry of school. The pedagogy of transfers and transitions at the Lower Austrian University College of Teacher Education(PH NÖ) Andreas Bieringer In M. Bernard s class, school

Mehr

Harry gefangen in der Zeit Begleitmaterialien

Harry gefangen in der Zeit Begleitmaterialien Episode 011 Grammar 1. Plural forms of nouns Most nouns can be either singular or plural. The plural indicates that you're talking about several units of the same thing. Ist das Bett zu hart? Sind die

Mehr

MgCl2/TiCl4-TMEDA/Al(i-Bu)3

MgCl2/TiCl4-TMEDA/Al(i-Bu)3 Diss. ETH Nr. 7590 POLYMERISATION UND COPOLYMERISATION VON PROPYLEN UND ETHYLEN MIT ZIEGLERNATTA TRÄGERKATALYSATOREN AUF MAGNESIUMCHLORIDBASIS DER ARTEN MgCl2/TiCl4/Al(iBu)3, MgCl2/TiCl4/Al(iBu)3/LEWISBASE

Mehr

Evaluation of an Augmented-Realitybased 3D User Interface to Enhance the 3D-Understanding of Molecular Chemistry

Evaluation of an Augmented-Realitybased 3D User Interface to Enhance the 3D-Understanding of Molecular Chemistry Evaluation of an Augmented-Realitybased 3D User Interface to Enhance the 3D-Understanding of Molecular Chemistry Patrick Maier, Gudrun Klinker Fachgebiet Augmented Reality (FAR),, Fakultät für Informatik,

Mehr

CNC ZUR STEUERUNG VON WERKZEUGMASCHINEN (GERMAN EDITION) BY TIM ROHR

CNC ZUR STEUERUNG VON WERKZEUGMASCHINEN (GERMAN EDITION) BY TIM ROHR (GERMAN EDITION) BY TIM ROHR READ ONLINE AND DOWNLOAD EBOOK : CNC ZUR STEUERUNG VON WERKZEUGMASCHINEN (GERMAN EDITION) BY TIM ROHR PDF Click button to download this ebook READ ONLINE AND DOWNLOAD CNC ZUR

Mehr

Themen für Seminararbeiten WS 15/16

Themen für Seminararbeiten WS 15/16 Themen für Seminararbeiten WS 15/16 Institut für nachhaltige Unternehmensführung Themenblock A: 1) Carsharing worldwide - An international Comparison 2) The influence of Carsharing towards other mobility

Mehr

Lehrstuhl für Allgemeine BWL Strategisches und Internationales Management Prof. Dr. Mike Geppert Carl-Zeiß-Str. 3 07743 Jena

Lehrstuhl für Allgemeine BWL Strategisches und Internationales Management Prof. Dr. Mike Geppert Carl-Zeiß-Str. 3 07743 Jena Lehrstuhl für Allgemeine BWL Strategisches und Internationales Management Prof. Dr. Mike Geppert Carl-Zeiß-Str. 3 07743 Jena http://www.im.uni-jena.de Contents I. Learning Objectives II. III. IV. Recap

Mehr

An Open Innovation Technology Transfer Concept - R&D Cooperation for breakthrough Technologies between Academic Spin-Offs and established Industry

An Open Innovation Technology Transfer Concept - R&D Cooperation for breakthrough Technologies between Academic Spin-Offs and established Industry Diss ETH NO. 20731 An Open Innovation Technology Transfer Concept - R&D Cooperation for breakthrough Technologies between Academic Spin-Offs and established Industry A dissertation submitted to ETH ZURICH

Mehr

Algorithms for graph visualization

Algorithms for graph visualization Algorithms for graph visualization Project - Orthogonal Grid Layout with Small Area W INTER SEMESTER 2013/2014 Martin No llenburg KIT Universita t des Landes Baden-Wu rttemberg und nationales Forschungszentrum

Mehr

HIR Method & Tools for Fit Gap analysis

HIR Method & Tools for Fit Gap analysis HIR Method & Tools for Fit Gap analysis Based on a Powermax APML example 1 Base for all: The Processes HIR-Method for Template Checks, Fit Gap-Analysis, Change-, Quality- & Risk- Management etc. Main processes

Mehr

Level 2 German, 2013

Level 2 German, 2013 91126 911260 2SUPERVISOR S Level 2 German, 2013 91126 Demonstrate understanding of a variety of written and / or visual German text(s) on familiar matters 9.30 am Monday 11 November 2013 Credits: Five

Mehr

CABLE TESTER. Manual DN-14003

CABLE TESTER. Manual DN-14003 CABLE TESTER Manual DN-14003 Note: Please read and learn safety instructions before use or maintain the equipment This cable tester can t test any electrified product. 9V reduplicated battery is used in

Mehr

There are 10 weeks this summer vacation the weeks beginning: June 23, June 30, July 7, July 14, July 21, Jul 28, Aug 4, Aug 11, Aug 18, Aug 25

There are 10 weeks this summer vacation the weeks beginning: June 23, June 30, July 7, July 14, July 21, Jul 28, Aug 4, Aug 11, Aug 18, Aug 25 Name: AP Deutsch Sommerpaket 2014 The AP German exam is designed to test your language proficiency your ability to use the German language to speak, listen, read and write. All the grammar concepts and

Mehr

Prediction of Binary Fick Diffusion Coefficients using COSMO-RS

Prediction of Binary Fick Diffusion Coefficients using COSMO-RS Prediction of Binary Fick Diffusion Coefficients using COSMO-RS Sebastian Rehfeldt, Tobias Sachsenhauser, Sandra Schreiber, Harald Klein Institute of Plant and Process Technology Technische Universität

Mehr

Soll der Staat aktiv Innovationen fördern? Das Beispiel Airbus A400M

Soll der Staat aktiv Innovationen fördern? Das Beispiel Airbus A400M Wirtschaft Tobias Karcher Soll der Staat aktiv Innovationen fördern? Das Beispiel Airbus A400M Bachelorarbeit Bibliografische Information der Deutschen Nationalbibliothek: Die Deutsche Bibliothek verzeichnet

Mehr

Hazards and measures against hazards by implementation of safe pneumatic circuits

Hazards and measures against hazards by implementation of safe pneumatic circuits Application of EN ISO 13849-1 in electro-pneumatic control systems Hazards and measures against hazards by implementation of safe pneumatic circuits These examples of switching circuits are offered free

Mehr

Unsymmetrical ansa-metallocenes of zirconium and hafnium W. A. Herrmann, M. J. A. Morawietz, Th. Priermeier J. Organomet. Chem. 506 (1996) 351-355.

Unsymmetrical ansa-metallocenes of zirconium and hafnium W. A. Herrmann, M. J. A. Morawietz, Th. Priermeier J. Organomet. Chem. 506 (1996) 351-355. Tin-bridged ansa-metallocenes of zirconium: synthesis and catalytic performance in olefin polymerization, M. J. A. Morawietz, H.-F. Herrmann, F. Küber J. Organomet. Chem. 509 (1996) 115-117. Unsymmetrical

Mehr

Corporate Digital Learning, How to Get It Right. Learning Café

Corporate Digital Learning, How to Get It Right. Learning Café 0 Corporate Digital Learning, How to Get It Right Learning Café Online Educa Berlin, 3 December 2015 Key Questions 1 1. 1. What is the unique proposition of digital learning? 2. 2. What is the right digital

Mehr

5. Ferrocentagung, 25. - 27. Februar 2007, TU Kaiserslautern. Programm

5. Ferrocentagung, 25. - 27. Februar 2007, TU Kaiserslautern. Programm 5. Ferrocentagung, 25. - 27. Februar 2007, TU Kaiserslautern Sonntag, 25. Februar 2007 Programm Montag, 26. Februar 2007 8:25-8:30 Begrüßung durch die Organisatoren 8:30-9:30 Plenarvortrag A. Togni 9:30-9:55

Mehr

PONS DIE DREI??? FRAGEZEICHEN, ARCTIC ADVENTURE: ENGLISCH LERNEN MIT JUSTUS, PETER UND BOB

PONS DIE DREI??? FRAGEZEICHEN, ARCTIC ADVENTURE: ENGLISCH LERNEN MIT JUSTUS, PETER UND BOB Read Online and Download Ebook PONS DIE DREI??? FRAGEZEICHEN, ARCTIC ADVENTURE: ENGLISCH LERNEN MIT JUSTUS, PETER UND BOB DOWNLOAD EBOOK : PONS DIE DREI??? FRAGEZEICHEN, ARCTIC ADVENTURE: Click link bellow

Mehr

INTERREG IIIa Project R&D - Ready for Research and Development Project results and ongoing activities

INTERREG IIIa Project R&D - Ready for Research and Development Project results and ongoing activities INTERREG IIIa Project R&D - Ready for Research and Development Project results and ongoing activities Györ, 5th December 2007 Key regions + perifary for surveys Background objectives CENTROPE needs a strategy

Mehr

NEWSLETTER. FileDirector Version 2.5 Novelties. Filing system designer. Filing system in WinClient

NEWSLETTER. FileDirector Version 2.5 Novelties. Filing system designer. Filing system in WinClient Filing system designer FileDirector Version 2.5 Novelties FileDirector offers an easy way to design the filing system in WinClient. The filing system provides an Explorer-like structure in WinClient. The

Mehr

Taking Electrophilic Trifluoromethylation Chemistry a Step Further

Taking Electrophilic Trifluoromethylation Chemistry a Step Further DISS. ETH No. 19219 Taking Electrophilic Trifluoromethylation Chemistry a Step Further A dissertation submitted to ETH ZURICH for the degree of Doctor of Sciences presented by RAFFAEL KOLLER MSc in Chemistry

Mehr

Accounting course program for master students. Institute of Accounting and Auditing http://www.wiwi.hu-berlin.de/rewe

Accounting course program for master students. Institute of Accounting and Auditing http://www.wiwi.hu-berlin.de/rewe Accounting course program for master students Institute of Accounting and Auditing http://www.wiwi.hu-berlin.de/rewe 2 Accounting requires institutional knowledge... 3...but it pays: Lehman Bros. Inc.,

Mehr

Scenario Building Workshop - Interplay of problem framings

Scenario Building Workshop - Interplay of problem framings Transdiciplinary Conference Inter- and Transdisciplinary Problem Framing, ETH Zürich, 27-28 November 2008 Scenario Building Workshop - Interplay of problem framings PD Dr. Rolf Meyer*, Dr. Martin Knapp*,

Mehr

A dissertation submitted to ETH ZURICH. for the degree of Doctor of Sciences. presented by ALEXANDER SCHILLING Dipl. Masch.-Ing.

A dissertation submitted to ETH ZURICH. for the degree of Doctor of Sciences. presented by ALEXANDER SCHILLING Dipl. Masch.-Ing. Diss. ETH No. 17764 Model-Based Detection and Isolation of Faults in the Air and Fuel Paths of Common-rail DI Diesel Engines Equipped with a Lambda and a Nitrogen Oxides Sensor A dissertation submitted

Mehr

Inequality Utilitarian and Capabilities Perspectives (and what they may imply for public health)

Inequality Utilitarian and Capabilities Perspectives (and what they may imply for public health) Inequality Utilitarian and Capabilities Perspectives (and what they may imply for public health) 1 Utilitarian Perspectives on Inequality 2 Inequalities matter most in terms of their impact onthelivesthatpeopleseektoliveandthethings,

Mehr

DKE Jahrestagung Frankfurt, 4. Dezember 2000

DKE Jahrestagung Frankfurt, 4. Dezember 2000 Bettina Drehmann Brennstoffzellen Fuel Cell Applications DaimlerChrysler Necar 4 205 kw Transit Buses 100 Watt System Ford P2000 250 kw Stationary Power Plant 1 kw System Forces driving Fuel Cells Environmental

Mehr

XONTRO Newsletter. Financial Institutes. No. 70

XONTRO Newsletter. Financial Institutes. No. 70 XONTRO Newsletter Financial Institutes No. 70 Page 1 This XONTRO Newsletter for Financial Institutes contains information covering the following topics: BCIN BV processing control handling ( Bearbeitung

Mehr

USBASIC SAFETY IN NUMBERS

USBASIC SAFETY IN NUMBERS USBASIC SAFETY IN NUMBERS #1.Current Normalisation Ropes Courses and Ropes Course Elements can conform to one or more of the following European Norms: -EN 362 Carabiner Norm -EN 795B Connector Norm -EN

Mehr

Technical Thermodynamics

Technical Thermodynamics Technical Thermodynamics Chapter 1: Introduction, some nomenclature, table of contents Prof. Dr.-Ing. habil. Egon Hassel University of Rostock, Germany Faculty of Mechanical Engineering and Ship Building

Mehr

Walter GPS Global Productivity System

Walter GPS Global Productivity System Walter GPS Global Productivity System DIE WERKZEUGAUSWAHL MIT dem ÜBERRASCHUNGS- EFFEKT. ÜBERRASCHEND EINFACH. THE TOOL SELECTION WITH THE ELEMENT OF SURPRISE. SURPRISINGLY EASY. Überraschend schnell:

Mehr

ONLINE LICENCE GENERATOR

ONLINE LICENCE GENERATOR Index Introduction... 2 Change language of the User Interface... 3 Menubar... 4 Sold Software... 5 Explanations of the choices:... 5 Call of a licence:... 7 Last query step... 9 Call multiple licenses:...

Mehr

Plattenkollektion Panel Collection

Plattenkollektion Panel Collection Plattenkollektion Panel Collection Acrylux Wir liefern 20 aktuelle Acrylux-Oberflächen auf unterschiedlichen Trägermaterialien und diversen Plattenstärken, einseitig oder beidseitig beschichtet. Die Flächen

Mehr

Rhodium-Catalyzed Imine-Directed C-H Bond Activation. Biomimetic Synthesis of Sesquiterpenoids

Rhodium-Catalyzed Imine-Directed C-H Bond Activation. Biomimetic Synthesis of Sesquiterpenoids Diss. ETH No. 21735 Rhodium-Catalyzed Imine-Directed C-H Bond Activation And Biomimetic Synthesis of Sesquiterpenoids A dissertation submitted to ETH ZURICH For the degree of Doctor of Sciences Presented

Mehr

Ways and methods to secure customer satisfaction at the example of a building subcontractor

Ways and methods to secure customer satisfaction at the example of a building subcontractor Abstract The thesis on hand deals with customer satisfaction at the example of a building subcontractor. Due to the problems in the building branch, it is nowadays necessary to act customer oriented. Customer

Mehr

Grade 12: Qualifikationsphase. My Abitur

Grade 12: Qualifikationsphase. My Abitur Grade 12: Qualifikationsphase My Abitur Qualifikationsphase Note 1 Punkte Prozente Note 1 15 14 13 85 % 100 % Note 2 12 11 10 70 % 84 % Note 3 9 8 7 55 % 69 % Note 4 6 5 4 40 % 54 % Note 5 3 2 1 20 % 39

Mehr

Possible Solutions for Development of Multilevel Pension System in the Republic of Azerbaijan

Possible Solutions for Development of Multilevel Pension System in the Republic of Azerbaijan Possible Solutions for Development of Multilevel Pension System in the Republic of Azerbaijan by Prof. Dr. Heinz-Dietrich Steinmeyer Introduction Multi-level pension systems Different approaches Different

Mehr

Exercise (Part VIII) Anastasia Mochalova, Lehrstuhl für ABWL und Wirtschaftsinformatik, Kath. Universität Eichstätt-Ingolstadt 1

Exercise (Part VIII) Anastasia Mochalova, Lehrstuhl für ABWL und Wirtschaftsinformatik, Kath. Universität Eichstätt-Ingolstadt 1 Exercise (Part VIII) Notes: The exercise is based on Microsoft Dynamics CRM Online. For all screenshots: Copyright Microsoft Corporation. The sign ## is you personal number to be used in all exercises.

Mehr

DAS ZUFRIEDENE GEHIRN: FREI VON DEPRESSIONEN, TRAUMATA, ADHS, SUCHT UND ANGST. MIT DER BRAIN-STATE-TECHNOLOGIE DAS LEBEN AUSBALANCIEREN (GE

DAS ZUFRIEDENE GEHIRN: FREI VON DEPRESSIONEN, TRAUMATA, ADHS, SUCHT UND ANGST. MIT DER BRAIN-STATE-TECHNOLOGIE DAS LEBEN AUSBALANCIEREN (GE DAS ZUFRIEDENE GEHIRN: FREI VON DEPRESSIONEN, TRAUMATA, ADHS, SUCHT UND ANGST. MIT DER BRAIN-STATE-TECHNOLOGIE DAS LEBEN AUSBALANCIEREN (GE READ ONLINE AND DOWNLOAD EBOOK : DAS ZUFRIEDENE GEHIRN: FREI

Mehr

Extract of the Annotations used for Econ 5080 at the University of Utah, with study questions, akmk.pdf.

Extract of the Annotations used for Econ 5080 at the University of Utah, with study questions, akmk.pdf. 1 The zip archives available at http://www.econ.utah.edu/ ~ ehrbar/l2co.zip or http: //marx.econ.utah.edu/das-kapital/ec5080.zip compiled August 26, 2010 have the following content. (they differ in their

Mehr

Routing in WSN Exercise

Routing in WSN Exercise Routing in WSN Exercise Thomas Basmer telefon: 0335 5625 334 fax: 0335 5625 671 e-mail: basmer [ at ] ihp-microelectronics.com web: Outline Routing in general Distance Vector Routing Link State Routing

Mehr

Prediction Market, 28th July 2012 Information and Instructions. Prognosemärkte Lehrstuhl für Betriebswirtschaftslehre insbes.

Prediction Market, 28th July 2012 Information and Instructions. Prognosemärkte Lehrstuhl für Betriebswirtschaftslehre insbes. Prediction Market, 28th July 2012 Information and Instructions S. 1 Welcome, and thanks for your participation Sensational prices are waiting for you 1000 Euro in amazon vouchers: The winner has the chance

Mehr

Context-adaptation based on Ontologies and Spreading Activation

Context-adaptation based on Ontologies and Spreading Activation -1- Context-adaptation based on Ontologies and Spreading Activation ABIS 2007, Halle, 24.09.07 {hussein,westheide,ziegler}@interactivesystems.info -2- Context Adaptation in Spreadr Pubs near my location

Mehr

Pilot Project Biogas-powered Micro-gas-turbine

Pilot Project Biogas-powered Micro-gas-turbine 1/18 Pilot Project Biogas-powered Micro-gas-turbine Supported by the Hessischen Ministerium für Wirtschaft, Verkehr und Landesentwicklung Speaker Details 2/18 Jan Müller Works at Institute of Solar Energy

Mehr

Presentation of a diagnostic tool for hybrid and module testing

Presentation of a diagnostic tool for hybrid and module testing Presentation of a diagnostic tool for hybrid and module testing RWTH Aachen III. Physikalisches Institut B M.Axer, F.Beißel, C.Camps, V.Commichau, G.Flügge, K.Hangarter, J.Mnich, P.Schorn, R.Schulte, W.

Mehr

Titelbild1 ANSYS. Customer Portal LogIn

Titelbild1 ANSYS. Customer Portal LogIn Titelbild1 ANSYS Customer Portal LogIn 1 Neuanmeldung Neuanmeldung: Bitte Not yet a member anklicken Adressen-Check Adressdaten eintragen Customer No. ist hier bereits erforderlich HERE - Button Hier nochmal

Mehr

Level 1 German, 2012

Level 1 German, 2012 90886 908860 1SUPERVISOR S Level 1 German, 2012 90886 Demonstrate understanding of a variety of German texts on areas of most immediate relevance 9.30 am Tuesday 13 November 2012 Credits: Five Achievement

Mehr

p^db=`oj===pìééçêíáåñçêã~íáçå=

p^db=`oj===pìééçêíáåñçêã~íáçå= p^db=`oj===pìééçêíáåñçêã~íáçå= Error: "Could not connect to the SQL Server Instance" or "Failed to open a connection to the database." When you attempt to launch ACT! by Sage or ACT by Sage Premium for

Mehr

After sales product list After Sales Geräteliste

After sales product list After Sales Geräteliste GMC-I Service GmbH Thomas-Mann-Str. 20 90471 Nürnberg e-mail:service@gossenmetrawatt.com After sales product list After Sales Geräteliste Ladies and Gentlemen, (deutsche Übersetzung am Ende des Schreibens)

Mehr

Level 1 German, 2016

Level 1 German, 2016 90886 908860 1SUPERVISOR S Level 1 German, 2016 90886 Demonstrate understanding of a variety of German texts on areas of most immediate relevance 2.00 p.m. Wednesday 23 November 2016 Credits: Five Achievement

Mehr

Role Play I: Ms Minor Role Card. Ms Minor, accountant at BIGBOSS Inc.

Role Play I: Ms Minor Role Card. Ms Minor, accountant at BIGBOSS Inc. Role Play I: Ms Minor Role Card Conversation between Ms Boss, CEO of BIGBOSS Inc. and Ms Minor, accountant at BIGBOSS Inc. Ms Boss: Guten Morgen, Frau Minor! Guten Morgen, Herr Boss! Frau Minor, bald steht

Mehr

Christ Water Technology Group

Christ Water Technology Group Christ Water Technology Group 1 / 10.10.2002 / Schmitt G. THREE DIVISIONS OF BWT GROUP BWT AG Christ Water Technology Group Aqua Ecolife Technologies FuMA-Tech (Industrial & Municipal Division) (Household

Mehr

Welche Rolle kann gemeinwohlorientierte Wissenschaft/Forschungspolitik für die Entwicklung und Umsetzung einer zukunftsfähigen Green Economy spielen?

Welche Rolle kann gemeinwohlorientierte Wissenschaft/Forschungspolitik für die Entwicklung und Umsetzung einer zukunftsfähigen Green Economy spielen? Welche Rolle kann gemeinwohlorientierte Wissenschaft/Forschungspolitik für die Entwicklung und Umsetzung einer zukunftsfähigen Green Economy spielen? - In welcher Verbindung stehen gemeinwohlorientierte

Mehr

Bosch Thermotechnik. Thermotechnology

Bosch Thermotechnik. Thermotechnology Bosch Thermotechnik Energy Plus Home with available technology Miriam Asbeck, Energy Plus Home Project Manager Press conference in Stuttgart Bosch Haus Heidehof, 5 May 2010 1 Energy Plus Home with available

Mehr

Fluid-Particle Multiphase Flow Simulations for the Study of Sand Infiltration into Immobile Gravel-Beds

Fluid-Particle Multiphase Flow Simulations for the Study of Sand Infiltration into Immobile Gravel-Beds 3rd JUQUEEN Porting and Tuning Workshop Jülich, 2-4 February 2015 Fluid-Particle Multiphase Flow Simulations for the Study of Sand Infiltration into Immobile Gravel-Beds Tobias Schruff, Roy M. Frings,

Mehr

ISO 15504 Reference Model

ISO 15504 Reference Model Process flow Remarks Role Documents, data, tools input, output Start Define purpose and scope Define process overview Define process details Define roles no Define metrics Pre-review Review yes Release

Mehr

Bayerisches Landesamt für Gesundheit und Lebensmittelsicherheit Pool water quality the German philosophy

Bayerisches Landesamt für Gesundheit und Lebensmittelsicherheit Pool water quality the German philosophy Bayerisches Landesamt für Gesundheit und Lebensmittelsicherheit Pool water quality the German philosophy Christiane Höller Bavarian Health and Food Safety Authority Legal regulations 1979 Federal Law on

Mehr

Rhodium and Iridium Coordinated Aminyl Radicals: Synthesis and Catalytic Applications

Rhodium and Iridium Coordinated Aminyl Radicals: Synthesis and Catalytic Applications Dissertation ETH No. 16946 Rhodium and Iridium Coordinated Aminyl Radicals: Synthesis and Catalytic Applications A dissertation submitted to the SWISS FEDERAL INSTITUTE OF TECHNOLOGY ZÜRICH for the degree

Mehr

1.9 Dynamic loading: τ ty : torsion yield stress (torsion) τ sy : shear yield stress (shear) In the last lectures only static loadings are considered

1.9 Dynamic loading: τ ty : torsion yield stress (torsion) τ sy : shear yield stress (shear) In the last lectures only static loadings are considered 1.9 Dynaic loading: In the last lectures only static loadings are considered A static loading is: or the load does not change the load change per tie N Unit is 10 /sec 2 Load case Ι: static load (case

Mehr

Reduction ofindigo: Kinetics andmechanism

Reduction ofindigo: Kinetics andmechanism Diss. ETB No. 15268 Reduction ofindigo: Kinetics andmechanism A dissertation submitted to the Swiss Federal Institute oftechnology (ETH), Zurich for the degree of Doctor oftechnical Seiences presented

Mehr

Employment and Salary Verification in the Internet (PA-PA-US)

Employment and Salary Verification in the Internet (PA-PA-US) Employment and Salary Verification in the Internet (PA-PA-US) HELP.PYUS Release 4.6C Employment and Salary Verification in the Internet (PA-PA-US SAP AG Copyright Copyright 2001 SAP AG. Alle Rechte vorbehalten.

Mehr

Evidence of strobilurine resistant isolates of A. solani and A. alternata in Germany

Evidence of strobilurine resistant isolates of A. solani and A. alternata in Germany Technische Universität München Evidence of strobilurine resistant isolates of A. solani and A. alternata in Germany H. Hausladen, B. Adolf and J. Leiminger outline introduction material and methods results

Mehr

p^db=`oj===pìééçêíáåñçêã~íáçå=

p^db=`oj===pìééçêíáåñçêã~íáçå= p^db=`oj===pìééçêíáåñçêã~íáçå= How to Disable User Account Control (UAC) in Windows Vista You are attempting to install or uninstall ACT! when Windows does not allow you access to needed files or folders.

Mehr

Geometrie und Bedeutung: Kap 5

Geometrie und Bedeutung: Kap 5 : Kap 5 21. November 2011 Übersicht Der Begriff des Vektors Ähnlichkeits Distanzfunktionen für Vektoren Skalarprodukt Eukidische Distanz im R n What are vectors I Domininic: Maryl: Dollar Po Euro Yen 6

Mehr

EVANGELISCHES GESANGBUCH: AUSGABE FUR DIE EVANGELISCH-LUTHERISCHE LANDESKIRCHE SACHSEN. BLAU (GERMAN EDITION) FROM EVANGELISCHE VERLAGSAN

EVANGELISCHES GESANGBUCH: AUSGABE FUR DIE EVANGELISCH-LUTHERISCHE LANDESKIRCHE SACHSEN. BLAU (GERMAN EDITION) FROM EVANGELISCHE VERLAGSAN EVANGELISCHES GESANGBUCH: AUSGABE FUR DIE EVANGELISCH-LUTHERISCHE LANDESKIRCHE SACHSEN. BLAU (GERMAN EDITION) FROM EVANGELISCHE VERLAGSAN DOWNLOAD EBOOK : EVANGELISCHES GESANGBUCH: AUSGABE FUR DIE EVANGELISCH-LUTHERISCHE

Mehr

Notice: All mentioned inventors have to sign the Report of Invention (see page 3)!!!

Notice: All mentioned inventors have to sign the Report of Invention (see page 3)!!! REPORT OF INVENTION Please send a copy to An die Abteilung Technologietransfer der Universität/Hochschule An die Technologie-Lizenz-Büro (TLB) der Baden-Württembergischen Hochschulen GmbH Ettlinger Straße

Mehr

Firefighting System on Container Vessels

Firefighting System on Container Vessels Firefighting System on Container Vessels Uwe-Peter Schieder Cargo fires Development of firefighting systems Analogy with fires in buildings Examples Firefighting options today Firefighting options tomorrow

Mehr

Brennersysteme Burner systems

Brennersysteme Burner systems Einbaulage der Brenner Installation position of burners Brennersysteme Zum Schutze der Umwelt wurden in den letzten Jahren erhebliche Anforderungen an die Industrie gestellt, um schädliche Emissionen zu

Mehr

LEBEN OHNE REUE: 52 IMPULSE, DIE UNS DARAN ERINNERN, WAS WIRKLICH WICHTIG IST (GERMAN EDITION) BY BRONNIE WARE

LEBEN OHNE REUE: 52 IMPULSE, DIE UNS DARAN ERINNERN, WAS WIRKLICH WICHTIG IST (GERMAN EDITION) BY BRONNIE WARE LEBEN OHNE REUE: 52 IMPULSE, DIE UNS DARAN ERINNERN, WAS WIRKLICH WICHTIG IST (GERMAN EDITION) BY BRONNIE WARE DOWNLOAD EBOOK : LEBEN OHNE REUE: 52 IMPULSE, DIE UNS DARAN EDITION) BY BRONNIE WARE PDF Click

Mehr

Simulation of a Battery Electric Vehicle

Simulation of a Battery Electric Vehicle Simulation of a Battery Electric Vehicle M. Auer, T. Kuthada, N. Widdecke, J. Wiedemann IVK/FKFS University of Stuttgart 1 2.1.214 Markus Auer Agenda Motivation Thermal Management for BEV Simulation Model

Mehr