PROFORMA INVOICE Nº: Date: 27/7/2007 Number of pages: 1 of 9

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1 Number of pages: 1 of 9 Terms and Conditions: Delivery Time: Validity: Payment: Prices: Installation: Warranty: Up to 5 months after reception of official order. 6 months Advanced payment in favor of Bruker. See Annex for bank information. Ex-Work Bruker BioSpin in Euros. Included. Please note that operations means like helium, nitrogen and power have to be provided by the customer at his expense. 12 months after acceptance, however not exceeding 30 months after shipment, on material; EXCEPT glassware, writing heads of disk and floppy unit, diskettes, hard disk cartridges, and parts subject to wear and tear as well as defects caused by inadequate handling. Item Quan P/N Description Curr. Price 1 1 AV500 SUPERCONDUCTING FOURIER NMR SPECTROMETER AVANCE III TM 500 MHz High Performance Digital NMR Spectrometer equipped as follows: MAGNET SYSTEM / LOCK High performance actively shielded UltraShield superconducting magnet system BC-117/54 54 mm bore (operation field at Tesla), helium hold time >150 days, (500 MHz) helium level meter with alarm function for low helium level; Standard magnet stand with vibration damping accessory, frequencies damped above ca. 5 Hz (500 MHz). SHIM SYSTEM/LOCK CHANNEL Bruker high performance Shim System (BOSS2) with control of orthogonal 34 shim gradients, low current and low heat dissipation design for optimum homogeneity. ( MHz) Bruker Smart Magnet Control System (BSMS) for shim and lock control and Digital Lock control unit, including: digital lock frequency generation with variable frequency for operation at selectable fixed field

2 Number of pages: 2 of 9 digital quadrature lock receiver fast field adjustments with sample-and-hold circuit shim control boards (SCB) with ultra-stable high-precision, low-noise shim current sources BSMS Shuttle: USB keypad with jog knob for manual adjustment of lock, rotation and shims; can be used remotely STAINLESS STEEL CABINET 0.83 x 0.63 x 1.3 m (depthwidth-height) RF SECTION Frequency Generation, Digital Control, and Acquisition System including: Fast Ethernet based communication and control system for bi-directional connection to the host computer Pulse generating system with a time based of highest precision for the ultimate timing accuracy; controls the entire spectrometer during NMR experiment including frequency synthesizer, transmitter, receiver and gradients, timing resolution is 12.5 ns. Frequency Generation (FCU s and SGU s) for two Channels (1 and 2) by digital frequency synthesis, frequency range each MHz; for generation of phase, amplitude and frequency using Direct Digital Synthesis (DDS). Provides <0.01 phase resolution and <0.005 Hz frequency resolution. Covering the entire NMR frequency range at the specified field above 6 MHz. Includes wave form memory for pulse shaping in frequency, amplitude and phase and composite-pulse decoupling generator for synchronous and asynchronous operation. Receiver control unit for NMR (DRU) signal accumulation with real-time digital filtering in combination with oversampling technology. The fast RISC co-processor with buffer memory ensures flexible real-time data management. High performance digitizer for superior and highly flexible data acquisition at ultimate digitizer dynamic range. Digital quadrature detection for complete elimination of quadspikes, artefacts in the center of the spectrum.

3 Number of pages: 3 of 9 TRANSMITTER / RECEIVER SYSTEM BLAXH300/100 Amplifier System including: high performance linear amplifier for observation or decoupling of 1H or 19F, with 100 W pulse power, max. 35 W average power in the range of 1H/19F high performance linear amplifier for the multinuclear range, with 300 W pulse power, max. 30 W average power in the range of MHz. Solid state power control for both channels over the entire power range. Includes routing capabilities for frequency / amplifier selection under full computer control. ATR transmitter/receiver system with high dynamic range, computer controlled indirect detection capability, quadrature detection. Multilink HPPR/2 Preamplifier (compatible with Bruker Cryoprobeheads ) 1H preamplifier, low noise GaAs design Broadband preamplifier 2H preamplifier for lock and 2H observation Microprocessor control Built in tune/match display. NMR WINDOWS XP WORKSTATION HP XW4400 workstation for the use with TopSpin software, equipped as follows: Mini-tower(449 x 457 x 170 mm) power supply: Dual range / V, 50/60Hz; 6 storage bays: 2 internal 3.5-inch (1 used, 1 free), 3 external 5.25-inch (2 used, 1 free), 1 external 3.5-inch (free) Intel Core2 Duo, E6600, 2.4GHz, 4 MB L2 Cache Intel 975X Express Chipsatz Slots: 1x PCIe (x16) graphics, 1x PCIe (x8), 1x PCIe (x1), 3x Legacy PCI 1 GB RAM (2 x 512 MB) PC DDR2 667 MHz ECC Integrated SATA 3GB/s Controller, RAID, 0, 1, 5,10 Disk: 160 GB, 3 GB/s, NCQ, SATA, 7200 rpm HP 16x DVD+/-RW DL, LightScribe Graphic adapter NVIDIA Quadro FX560, 128 MB, PCI-E

4 Number of pages: 4 of 9 Network adapters: 1x on board (BROADCOM based) 10/100/1000 Mbits/s (NET), 1x HP/BROADCOM PCI-E network adapter 10/100/1000 Mbits/s (SPECT) Sound AC 97, 16 bit, on board, internal loudspeaker HP Optical Scroll Mouse, USB Interfaces: 1x parallel, and 1x serial, 2x USB 2.0 (front), 6x USB (rear), 1x PS/2 keyboard, 1x PS/2 mouse, sound in/out Power supply: Dual range / V, 50/60Hz HP Enhanced Keyboard PS/2 US English or UK English Operating system: Microsoft Windows XP MUI (= Multi language User Interface) with Service Pack 2 Virus software GDATA AntiVirenKit Prof. engl. incl. one year support (pre-installed, license without media) Backup/Drive image software ACRONIS True Image 10.x English" Bruker Toolkit 19" TFT monitor Without 3.5 diskette drive NMR Suite (TOPSPIN) including: NMR data acquisition program (arbitrary dimensions) and processing and display program for 1D, 2D, 3D,4D for liquid and solid state experiments. ICON NMR, automation program used with and without sample changer. TOPSPIN-PLOT, data printing program. NMRSIM, Experiments simulation program for 1D and 2D including shape pulses and gradient simulation. NMRCHECK, Instrument checking program for all parts of the spectrometer. NMRGUIDE NMR encyclopedia interactive HTML base guide for the study and understanding of NMR DOSY processing is included into TOPSPIN program. 2 1 AH0161 Computer desk for host computer (workstation) and for printer/plotter (required if not customer supplied). 3 1 AP1413 HP Laser Jet or equivalent for printing of text and spectra, single sheet, DIN A4 format, black and white incl. cable.

5 Number of pages: 5 of AH0070 Helium Transfer Line for the helium refill of the magnet. 5 1 AH0087 Nitrogen Separator 6 1 AH0206 Gradient Accessory GRASP II accessory; z-gradient electronics for Avance spectrometers consisting of gradient control unit (GCU) and 10A amplifier, for probeheads equipped with actively shielded z- gradient coil. Capability of gradient pulse strength of up to 50 Gauss/cm. 7 1 AH0003 Temperature Control Unit B-VT 3200 Bruker Variable temperature controller for temperatures above room temperature including standard accessory kit (thermocouple, heater and cables, etc.). Settable in 0.1ºC steps, Precision < 0.1ºC 8 1 AH0020 Low temperature accessory with 26 l LN2 dewar, evaporator and PUR transfer line for operation with LN2; low temperature limit ca C with 5mm probeheads and B-ST; effective temperature range depending on probehead 9 1 PH1102-Z PROBEHEADS TBI-Z triple Resonance broadband inverse probehead, 1H observe/decoupling, 2H lock, 13C and BB decoupling/observe standard range BB=31P-15N, 5 mm sample diameter. Equipped with gradient coil Z. Maximum gradient strength of up to 55 Gauss/cm. Operating temperature range from 150º up to +180º with 0.1º precision. On request, the 1H channel can be tuneable to 19F PH1152-Z BBO-Z broadband Observe probehead, BB Observe /decoupling; standard range BB=31P-109Ag and 1H or 19F observe/decoupling, 2H lock, 5 mm sample diameter. Equipped with gradient coil Z. Maximum gradient strength of up to 55 Gauss/cm.

6 Number of pages: 6 of 9 Operating temperature range from 150º up to +180º with 0.1º precision PH0702 CPMAS Accessories VTN CP/MAS Probehead, SB, broadband CPMAS probehead with BB range 15N-31P + 1H separated channel. Rotor size 4mm, Temperature range C, 1 x Filter 1H Pass High Power. 1 x Filter Band Pass (15N up to 31P) High Power AH0220 Fully automated pneumatic unit featuring: automated spinning up and down of rotors, precise spinning rate stabilization, automated eject, trigger output for synchronization with rotation, remote control by RS232C interface for automated operation, manual keyboard for local operation, and status indicator 13 1 AH0221 MAS Rotor transfer system for 4 mm rotors BH0362 MAS accessory set for handling of samples including: spoon, mortar and pestle 15 1 PH0762 G HRMAS Accessory (Semi Solid Sample) Dual 1H/13C inverse HR MAS probehead, 2H-lock, 4mm equipped with Magic Angle gradient. Rotor size 4mm, Temperature range C, 16 7 HZ05537 Rotor for HRMAS 12ul including caps HZ07213 Rotor for HRMAS 50ul including caps K1910 CPMAS rotors, 4mm, ea. incl. upper teflon spacer, sealing screw and 3 Kel-F caps 19 3 SHS300W TOPSPIN Processing license including: Silberstr eifen

7 Number of pages: 7 of 9 NMR data processing and display program for 1D, 2D, 3D, for liquid and solid state experiments. TOPSPIN-PLOT, data printing program. NMRSIM, Experiments simulation program for 1D and 2D including shape pulses and gradient simulation. DOSY processing is included into TOPSPIN program AH0085 Uninterrupted Power Supply with 4 KVA power AH AH0099 ATLAS COPCO SF2 8P Air Oil free Compressor including Absorption Air dryer CD6 Compressor: Max air flow: 180 liters /minutes at 5 bar. Max pressure 7 Bar Air buffer tank 100 liters Oil free scroll technology. Automatic water drain. Power supply country specific. Includes additional refrigeration air dryer for above compressors for tropical environment Air Dryer: Maximum flow 21 m3/h Dew point -40 ºC Designed for the use with highly sophisticated NMR experiments BH2070 Frequency Generation (FCU s and SGU s) for Channels 3 by digital frequency synthesis, frequency range each MHz; for generation of phase, amplitude and frequency using Direct Digital Synthesis (DDS). Provides <0.01 phase resolution and <0.005 Hz frequency resolution. Covering the entire NMR frequency range at the specified field above 6 MHz. Includes wave form memory for pulse shaping in frequency, amplitude and phase and composite-pulse decoupling generator for synchronous and asynchronous operation BH2081 BLAX300 Amplifier System including: High performance linear amplifier for the multinuclear range, with 300 W pulse power, max. 30 W average power in the range of 6-

8 Number of pages: 8 of MHz. Solid state power control the entire power range. Includes routing capabilities for frequency / amplifier selection under full computer control Training Installation and Trainings Installation of the instruments and training includes: Complete installation of the 500 MHz instrument Training of operation on the 500 MHz just after the installation by the service engineer. This includes practical training for operation and preventive maintenance training during one week Training of operation on the 500 MHz for CPMAS and HRMAS during the year after the installation. This includes practical training for operation and preventive maintenance training during one week Participation of one person to the Bruker NMR course course at the Bruker facilities in Karlsruhe. Bruker organizes several training courses concerning advanced NMR applications during one week. The participation includes:flight ticket from Brasil to Karlsruhe, Accomodation and Training. This training can be done at any time Warranty One year extra warranty including travel and accommodation. Excluding parts. BRUKER BioSpin GmbH Sylvain MEGUELLATNI Special Price to Dr. Luciano Liao: 450, Packing for Air Freight: 1, Price Ex-Work Bruker BioSpin GmBH: 451,500.00

9 Number of pages: 9 of 9 ANNEX: Classificação fiscal NCM Nº Peso: 1 box 092x092x188cm = 516kg net / 621kg gross 1 box 105x091x155cm = 280kg net / 365kg gross 1 box 184x149x156cm = 357kg net / 520kg gross 1 box 099x099x142kg = 202kg net / 290kg gross 1 box 189x062x084cm = 53kg net / 123kg gross Dados bancários para pagamento: Bank name: DRESDNER BANK KARLSRUHE Account Owner: Bruker BioSpin GmBH Bank Code BLZ: Account number: IBAN: DE S.W.I.F.T.-BIC: DRES DE FF Dresdner Bank AG, Karlsruhe Branch Karl-Friedrich-Str. 7, D Karlsruhe Forma de pagamento ANTECIPADO Transporte - EX-WORK

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