AR-16-GF ,3,7,8-TetraCDF

Transkript

1 Eurofins GfA Lab Service GmbH Neuländer Kamp 1 a D Hamburg GERMANY Tel: Fax: dioxins@eurofins.de Environnement S. A. attn. Herr Jürgen Reinmann Benzstraße Bad Homburg Person in charge ASM Dr. D. Stegemann Dr. D. Stegemann Report date {77A44D4F-679D-4FED-8E9 Page 1/6 Analytical report AR-16-GF ÌAR-16-GF-Ç$WYÈ-01AÎ Reference Amesa "Niederlande- Projekt" Probenahmevolumen: 512,1 Nm³ Das ausgewiesene Normvolumen bezieht sich auf einen Sauerstoffgehalt von 11%. Sample sender Herr Jürgen Reinmann Reception date time Transport by UPS Client sample code Omrin 19 Packaging Emissions-Set Number of containers 1 Reception temperature room temperature End analysis Test results CY107 PCDD/F ~ 17 congeneres ~ emission (EN 1948) ( ) (#) Method EN 1948, GLS DF 100, GC-HRMS 2,3,7,8-TetraCDD ,2,3,7,8-PentaCDD ,2,3,4,7,8-HexaCDD ,2,3,6,7,8-HexaCDD ,2,3,7,8,9-HexaCDD ,2,3,4,6,7,8-HeptaCDD OctaCDD ,3,7,8-TetraCDF ,2,3,7,8-PentaCDF ,3,4,7,8-PentaCDF

2 Page 2/6 1,2,3,4,7,8-HexaCDF ,2,3,6,7,8-HexaCDF ,2,3,7,8,9-HexaCDF < ,3,4,6,7,8-HexaCDF ,2,3,4,6,7,8-HeptaCDF ,2,3,4,7,8,9-HeptaCDF OctaCDF WHO(1998)-PCDD/F TEQ (lower-bound) WHO(1998)-PCDD/F TEQ (upper-bound) WHO(2005)-PCDD/F TEQ (lower-bound) WHO(2005)-PCDD/F TEQ (upper-bound) I-TEQ (NATO/CCMS) (lower-bound) I-TEQ (NATO/CCMS) (upper-bound) RR 13C12-1,2,3,7,8-PentaCDF 48.1 % RR 13C12-1,2,3,7,8,9-HexaCDF 64.6 % RR 13C12-1,2,3,4,7,8,9-HeptaCDF 66.1 % CY114 RR 13C12-PCDF/D ~ internal standards ( ) (#) Method Internal method, GLS DF 100, Calculation RR 13C12-2,3,7,8-TetraCDD 79.5 % RR 13C12-1,2,3,4-TetraCDD 100 % RR 13C12-1,2,3,7,8-PentaCDD 104 % RR 13C12-1,2,3,4,7,8-HexaCDD 103 % RR 13C12-1,2,3,6,7,8-HexaCDD 102 % RR 13C12-1,2,3,7,8,9-HexaCDD 100 % RR 13C12-1,2,3,4,6,7,8-HeptaCDD 102 % RR 13C12-OctaCDD 84.8 % RR 13C12-2,3,7,8-TetraCDF 76.6 % RR 13C12-2,3,4,7,8-PentaCDF 104 % RR 13C12-1,2,3,4,7,8-HexaCDF 94.3 % RR 13C12-1,2,3,6,7,8-HexaCDF 91.2 % RR 13C12-2,3,4,6,7,8-HexaCDF 106 % RR 13C12-1,2,3,4,6,7,8-HeptaCDF 95.9 % RR 13C12-OctaCDF 93.6 % CY040 PCB ~ dioxin-like / 12 WHO ~ emission / air ( ) (#) Method Internal method, GLS DF 100, GC-HRMS PCB PCB PCB 105 < PCB

3 Page 3/6 PCB 118 < PCB PCB PCB 156 < PCB PCB PCB PCB WHO(1998)-PCB TEQ (lower-bound) WHO(1998)-PCB TEQ (medium-bound) WHO(1998)-PCB TEQ (upper-bound) WHO(2005)-PCB TEQ (lower-bound) WHO(2005)-PCB TEQ (medium-bound) WHO(2005)-PCB TEQ (upper-bound) RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % CY053 RR 13C12-PCB ~ internal standards ( ) (#) Method Internal method, GLS DF 100, Calculation RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB % RR 13C12-PCB %

4 Page 4/6 GF082 PBDD/F ~ 11 congeners ~ environm. / emiss. / air ( ) Method Internal method,, GC-HRMS 237-TriBDD < ,3,7,8-TetraBDD < ,2,3,7,8-PentaBDD < ,2,3,4,7,8-/ 1,2,3,6,7,8-HexaBDD < ,2,3,7,8,9-HexaBDD < TriBDF ,3,7,8-TetraBDF < ,2,3,7,8-PentaBDF < ,3,4,7,8-PentaBDF < ,2,3,4,7,8-/1,2,3,6,7,8-HexaBDF < ,2,3,4,6,7,8-HeptaBDF < CYR18 PBB (polybrominated biphenyls) ~ emission/air ( ) Method Internal method, GLS OC 204, GC-MS 2,2',5,5'-TetraBB # 52 < ,2',4,5,5'-PentaBB # 101 < ,2',4,4',5,5'-HexaBB # 153 < ,2',3,4,4',5,5'-HeptaBB # BB 180 < ,2',3,3',4,4',5,5'-OctaBB # BB 194 < ,2',3,3',4,4',5,5',6-NonaBB # BB 206 < DecaBB # 209 < sum of analysed BBs (excl. LOQ) ND sum of analysed BBs (incl. LOQ) CYR23 PBDE ~ (LR) ~ emission / air ( ) (#) Method Internal method, GLS OC 200, GC-MS 2,2',4-TriBDE (BDE-17) < ,4,4'-TriBDE (BDE-28) < sum of analysed TriBDEs (excl. LOQ) ND sum of analysed TriBDEs (incl. LOQ) ,2,4,4 -TetraBDE (BDE-47) < ,2',4,5'-TetraBDE (BDE-49) < ,3,4,4 -TetraBDE (BDE-66) < ,3,4,6-TetraBDE (BDE-71) < ,3,4,4 -TetraBDE (BDE-77) < sum of analysed TetraBDEs (excl. LOQ) ND sum of analysed TetraBDEs (incl. LOQ) ,2,3,4,4 -PentaBDE (BDE-85) < ,2,4,4,5-PentaBDE (BDE-99) <

5 Page 5/6 2,2',4,4',6-PentaBDE (BDE-100) < ,3,4,4,6-PentaBDE (BDE-119) < ,3',4,4',5-PentaBDE (BDE-126) < sum of analysed PentaBDEs (excl. LOQ) ND sum of analysed PentaBDEs (incl. LOQ) ,2',3,4,4',5'-HexaBDE (BDE-138) < ,2,4,4,5,5 -HexaBDE (BDE-153) < ,2',4,4',5,6'-HexaBDE (BDE-154) < ,3,3',4,4',5-HexaBDE (BDE-156) < sum of analysed HexaBDEs (excl. LOQ) ND sum of analysed HexaBDEs (incl. LOQ) ,2,3',4,4,5',6-HeptaBDE (BDE-183) < ,2',3,4,4',6,6'-HeptaBDE (BDE-184) < ,3,3',4,4',5',6-HeptaBDE (BDE-191) < sum of analysed HeptaBDEs (excl. LOQ) ND sum of analysed HeptaBDEs (incl. LOQ) ,2',3,4,4',5,5',6-OctaBDE (BDE-196) < ,2',3,3',4,4',6,6'-OctaBDE (BDE-197) < sum of analysed OctaBDEs (excl. LOQ) ND sum of analysed OctaBDEs (incl. LOQ) ,2',3,3',4,4',5,5',6-NonaBDE (BDE-206) < ,2',3,3'4,4',5,6,6'-NonaBDE (BDE-207) < sum of analysed NonaBDEs (excl. LOQ) ND sum of analysed NonaBDEs (incl. LOQ) DecaBDE (BDE-209) < Sum of analysed BDEs (excl. LOQ) ND Sum of analysed BDEs (incl. LOQ) GFFC5 PFOS + PFOA ~ materials ( ) (#) Method Internal method, GLS OC 400, LC-MS/MS Perfluorooctane sulfonate (PFOS) < Perfluorooctanoic acid (PFOA) total PFOS / PFOA excl. LOQ total PFOS / PFOA incl. LOQ ( ) = The test was performed at the laboratory site: Am Neuländer Gewerbepark 4 (#) = Eurofins GfA Lab Service GmbH (Hamburg) is accredited for this test. < - Concentration below the indicated limit of quantification (LOQ) ND - not determined since none of the corresponding congeners was above the LOQ

6 Page 6/6

7 Standard AMESA Record Plant Operator: OMRIN - NL Plant: REC - Harlingen -NL Sampling Location: Exhaust gas Sample No.: Measurement no. 19 Start: :44 End: :16 Sampling Period: 671 h Remarks Interruptions < 30 min are not included Daily (Average) Records Date Sample Volume O 2 - Concentration a O 2 - Correction Factor b O 2 - Correction Factor b (total, Nm 3 ) (Vol.- %, dry) (x % O 2-11% O 2 ) (acc. to German 17.BImSchV) ,561 9,40 0,863 1, ,467 9,35 0,859 1, ,075 9,25 0,852 1, ,291 9,12 0,842 1, ,859 9,18 0,847 1, ,335 9,12 0,842 1, ,385 9,39 0,862 1, ,468 9,38 0,861 1, ,143 9,27 0,853 1, ,891 9,39 0,862 1, ,584 9,22 0,850 1, ,003 9,06 0,838 1, ,833 9,08 0,839 1, ,951 9,26 0,852 1, ,826 9,20 0,849 1, ,923 8,88 0,825 1, ,915 8,93 0,829 1, ,055 8,90 0,827 1, ,323 8,89 0,826 1, ,266 8,76 0,817 1, ,149 8,62 0,808 1, ,953 8,60 0,807 1, ,908 8,95 0,831 1, ,362 8,94 0,830 1, ,731 8,94 0,830 1, ,315 9,03 0,836 1, ,670 8,68 0,812 1, ,047 8,75 0,817 1, ,636 8,59 0,806 1,000 Reference Total Average Average Average Period (corrected by volume) (corrected by volume) to 428,636 9,04 0,837 1, a: measured by plant operator b: calculated from 0.5 h averages c: AMESA not in operation